Can a DC Current Replicate the Glow of Hydrogen Peroxide in Glow Sticks?

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The discussion centers on the chemistry of glow sticks, specifically the role of hydrogen peroxide in exciting fluorescent dyes to produce light. It questions whether applying a DC current could achieve a similar effect, but clarifies that the initial understanding of electron involvement is incorrect. Alternatives for exciting fluorescent dyes include using electric fields or heat, with voltage-sensitive dyes being a potential solution. Examples of such dyes are found in cell biology and neuroscience, typically involving fluorescent proteins. The conversation concludes with a suggestion to place the dye between charged plates to explore this method.
kateman
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So from my understanding of glow sticks, the decomposition of hydrogen peroxide provides electrons that excites the fluorescent dye and gives off that classical glow-stick light source.

My question is, could one put a DC current over the solution and still theoretically obtain the same result? If not, what could be done to achieve it from the glow stick dye [other than to put more hydrogen peroxide in there]?

Thanks,
Kateman
 
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So from my understanding of glow sticks, the decomposition of hydrogen peroxide provides electrons that excites the fluorescent dye
... that would not be a good understanding of how a glowstick works. Looking at the chemistry I don't see stray electrons there.

The other side of your question though: there are lots of ways to excite a florescent dye. You can certainly find a dye that will be excited in the presence of an electric field.

I take it you have used-up glow-sticks you'd like to see glow again?
I have not heard of them getting exited in electric fields. I have heard you can get them to light up again using heat. Not tried.
 
Simon Bridge said:
...there are lots of ways to excite a florescent dye. You can certainly find a dye that will be excited in the presence of an electric field.

Thanks Simon, much appreciated - can you please give an example of a dye that could do this with either an electric field or current? I tried looking it up, but did not return anything useful.
 
More like you'd look for voltage sensitive dyes - they are used in cell biology and neuroscience. iirc: usually some kind of florescing protein.

You'd put a vial of your dye between two charged plates :)
 
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