Can Metals React with Water in Addition to Acids?

AI Thread Summary
Metals react with acids to produce salts and water, but their reactivity with water varies significantly. Sodium, being highly reactive, will preferentially react with water rather than displacing zinc from zinc sulfate solution. This is due to its strong tendency to form hydroxides when in contact with water. In contrast, less reactive metals like gold do not exhibit this behavior. When magnesium reacts with hydrochloric acid, it produces magnesium chloride and hydrogen gas, and the presence of water does not alter the overall stoichiometry of the reaction significantly. The reaction of magnesium with water to form magnesium hydroxide is secondary and does not affect the calculations for the acid reaction, as the water produced can be considered to cancel out in the overall equation. The discussion emphasizes the importance of understanding the reactivity series of metals and how it influences their interactions with acids and water.
sgstudent
Messages
726
Reaction score
3
Metals will react with acid to form a salt and water. But won't the metal also react with water to form an hydroxide? Similarly, when I put sodium metal into a zinc sulfate solution will displacement occur or will the sodium react with water? Thanks for the help!
 
Chemistry news on Phys.org
What do you think? Remember that different metals have different properties.Compare,for example,sodium with gold.
 
Dadface said:
What do you think? Remember that different metals have different properties.Compare,for example,sodium with gold.

Sodium is more reactive so it will react with water? But why won't it displace but instead react with water? Also I'm unsure why won't the sodium also react with water...

Thanks for the help!
 
Sodium has not time to react with dissolved Zn - it will react with water first, just because of the very high reactivity. Some metals can be reduced with metallic sodium, but it is done not in the solution, but in the molten salts. See for example: http://pubs.acs.org/doi/abs/10.1021/ba-1957-0019.ch014

I seem to remember one of the light elements was first prepared in the pure form bu the sodium reduction, but for the life of me, I can't remember details.
 
Oh ok. Thanks for the help.:) then also, when I react eg Mg with HCl, Mg+2HCl-->MgCl2+H2. Then when I do the mole calculation I'll use this reactions to determine my values? So I ignore the reaction of metals and water? Reaction:Mg+2H2O-->Mg(OH)2+H2
 
Last edited:
Even if you have a reaction of Mg with water, it doesn't matter. What happens to the Mg(OH)2 in the presence of acid? What is the overall reaction?
 
Borek said:
Even if you have a reaction of Mg with water, it doesn't matter. What happens to the Mg(OH)2 in the presence of acid? What is the overall reaction?

I know that it would produce a salt too, but won't the calculations be different?
 
Write overall reaction equation.
 
Borek said:
Write overall reaction equation.

Mg+H2O+2HCL>MgCl2+H2+H2O Ohh, the H2O produced would cancel out!
 
  • #10
Borek, you are a genius.
 
  • #11
Quite the opposite, but I will spare you details.
 
Back
Top