Carrier concentration temperature dependence; semiconductors

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SUMMARY

The discussion focuses on the temperature dependence of majority and minority carrier concentrations in N- and P-type semiconductors, specifically addressing the challenges in calculating these concentrations in the "freeze out" region. The user references Pierret's "Semiconductor Device Fundamentals" and seeks to generate accurate curves using equations that account for both extrinsic and intrinsic regions. The conversation highlights the limitations of existing equations and the need for effective mass adjustments based on temperature, as well as the use of Silvaco ATLAS for simulation. A critical insight is that the formula for electron concentration (n) is only valid under full ionization of donor and acceptor states, necessitating adjustments using Fermi-Dirac statistics.

PREREQUISITES
  • Understanding of semiconductor physics, particularly N- and P-type materials
  • Familiarity with Fermi-Dirac statistics and its application in carrier concentration calculations
  • Knowledge of effective mass concepts in semiconductors
  • Experience with simulation tools like Silvaco ATLAS for device modeling
NEXT STEPS
  • Study the impact of temperature on carrier concentrations in semiconductors using Fermi-Dirac statistics
  • Explore the concept of effective mass and its temperature dependence in semiconductor materials
  • Learn to use Silvaco ATLAS for simulating semiconductor behavior under varying temperature conditions
  • Research the mathematical derivation of carrier concentration equations in the freeze-out region
USEFUL FOR

This discussion is beneficial for semiconductor physicists, electrical engineers, and researchers involved in device modeling and simulation, particularly those focused on temperature effects in semiconductor materials.

DivGradCurl
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Hi all,

I'm reviewing device physics and I would like to understand how majority and minority carrier concentrations for both N- and P-type substrates change with temperature. My reference, Pierret's Semiconductor Device Fundamentals, has this figure:

Figure.png


and I want to generate curves for all cases. However, I'm only given these equations

Table.png


which only seem to cover the extrinsic and intrinsic regions; it doesn't work for "freeze out". Here is what I get using the "n, p, and Fermi Level Computational Relationships":

Screen_Shot_2016_07_19_at_10_10_40_PM.png


Mathematica notebook download link:
https://drive.google.com/open?id=0ByhrqgHUHYVjaVdHM3UwNUlWSHc

which obviously does not match the figure above. I also wonder how the characteristic looks like for minority carriers, and I would like to repeat the figure for the P-type substrate case.

I checked a number of references, but could not find expressions that yield the desired result. I did find a figure generated in Silvaco ATLAS:

tft_fig1.gif


Article:
http://www.silvaco.com/tech_lib_TCAD/simulationstandard/2000/nov/a1/a1.html

However, the calculation is not explained, which makes sense; it's a commercial software. It seems that the "freeze out" region is not simple to calculate as I could not find expressions in books. It appears to me that the carrier effective mass is a function of temperature, but books provide only 300K values, and that may be necessary if the correct expressions for the general case are those that rely on integrals and effective masses.

Can someone explain this? A hand-drawn sketch explaining the majority and minority carrier concentration as a function of temperature for both N- and P-type Si would be fine, if you happen to understand all cases. If you also know what's going wrong with my calculation, also let me know.

Thanks!
 

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Hi,

The problem is with the formula for n, (that is the first formula under "n, p and Fermi level computational relationships"). This formula is valid only if all the donor and acceptor states are fully ionized. Multiply ##N_D## and ##N_A## by the probability that the level is ionized (use Fermi-Dirac statistics and consider degeneracy of the level) then you should get the freeze-out
 

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