Charge Capacity of an Electrode Based On Its Material

In summary, the practical capacity of a cathode material for a lithium-ion battery can be calculated using the voltage-time curve from a galvanostatic cycling test. This formula takes into account factors such as current density, area, cut-off potential, and molecular weight of the active material. The theoretical capacity is typically higher than the practical capacity due to limitations in removing all of the lithium from the material during cycling. In contrast, the capacitance of a parallel plate capacitor is primarily determined by the dielectric constant of the insulation and is not affected by the conductor material.
  • #1
HelloCthulhu
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Recently I've been researching parallel plate capacitors and was wondering what effects the material had on the charge capacity of the plate. I found one source for measuring the capacity based on its material, but haven't seen any textbook evidence to support it yet. Any feedback on the accuracy of the formula is greatly appreciated.

https://www.researchgate.net/post/How_do_I_calculate_the_theoretical_capacity_of_a_cathode_material_LiMn15Ni05O4_for_lithium_ion_battery

"The Practical specific capacity can be calculated as follow by the Voltage-time curve from the galvanostatic cycling test:

Qpractical = (i*A*tcut off ) / ( 3600*Mw) mAh g-1

where:

i is the current density in A m-2

A the area in m2

tcutoff is the time to reach the cut off potential (Vcutoff) in seconds

Mw is the molecular weight of the active material used in the electrode.

For example for the LiNi1/3Co1/3Mn1/3O2 cathode material

The Theoretical capacity is Q=277.8 mAh g-1 (considering Mw= 96.46 g/mol and n=1) The Practical capacity:

Depends on the C rate used and also on the voltage range investigated (cut off voltage values). When cycled at C/30 in the 2.5-4.3V voltage range LiNMC generally delivers 165 mAh g-1.

The reason why practical capacity is lower than theoretical capacity is that not all the Li can be removed from the lattice of the host material. The rest of the Li is removed above the cutoff potential. Therefore, it is not accessible."
 
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  • #2
HelloCthulhu said:
Recently I've been researching parallel plate capacitors and was wondering what effects the material had on the charge capacity of the plate.
A chemical cell or a battery of cells is quite different to an electrical capacitor.

In a capacitor, where C = q / v; the capacitance is due only to the dielectric constant of the insulation, and is quite independent of the conductor material.

In a chemical cell, the voltage is determined by the electro-chemistry of the chemicals in the electrolyte and chemical reaction with the conductive plates.
 
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  • #3
Baluncore said:
In a chemical cell, the voltage is determined by the electro-chemistry of the chemicals in the electrolyte and chemical reaction with the conductive plates.

Thank you for the clarification! I was worried the usual capacitor math wouldn't be as exact.
 

Related to Charge Capacity of an Electrode Based On Its Material

1. What is the charge capacity of an electrode?

The charge capacity of an electrode refers to the maximum amount of charge that can be stored or released by the electrode during a chemical reaction.

2. How is the charge capacity of an electrode determined?

The charge capacity of an electrode is determined by the material it is made of and its surface area. Different materials have different charge storage capabilities, and a larger surface area allows for more ions to be stored.

3. What materials have a high charge capacity?

Materials such as lithium, cobalt, and nickel have a high charge capacity and are commonly used in rechargeable batteries. These materials have the ability to store and release a large number of ions, making them suitable for high-capacity energy storage.

4. How does the charge capacity of an electrode affect battery performance?

The charge capacity of an electrode directly affects the energy density and overall performance of a battery. A higher charge capacity means the battery can store more energy, resulting in longer battery life and higher power output.

5. Can the charge capacity of an electrode be improved?

Scientists are continuously researching and developing new materials and technologies to improve the charge capacity of electrodes. By finding new materials with higher charge storage capabilities and optimizing the electrode design, it is possible to improve the charge capacity and performance of batteries.

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