Clausius inequality temperature

In summary, the Clausius inequality states that the temperature at the interface between the system and the surroundings is the key factor in determining the direction of heat transfer and the irreversibility of the process. The temperature at the interface is usually not uniform in an irreversible process, and the inequality can be more precisely represented by an area and time integral equation. This principle is known as the principle of entropy increase for a control volume, as described by Borgnakke and Sonntag.
  • #1
LKmPV
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in the clausius inequality is the temperature that of the system or of the surroundings? or is it temperature of the body receiving positive heat?
(assuming the irreversibility is due to heat transfer with finite temperature difference)
[borgnakke and sonntag-principle of entropy increase for control volume]
 
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In the Clausius inequality, T is the temperature at the interface between the system and the surroundings, at the location where dQ is entering. In an irreversible process, the temperature within the system is not usually uniform.

A more precise representation of the Clausius inequality is given by:
[tex]ΔS≥\int_0^t\int_A{(\frac{\vec{q }}{T})\centerdot \vec{n} dA}dt[/tex]
where [itex]\vec{q}[/itex] is the local heat flux vector at the interface, [itex]\vec{n}[/itex] is an inwardly directed unit normal across the interface drawn from the surroundings to the system, and T is the temperature at the interface. The area integral is over the entire instantaneous interface between the system and the surroundings (the interface may be moving during the process), and the time integral is over the (irreversible) process from the initial thermodynamic equilibrium state to the final equilibrium state.
 

1. What is the Clausius inequality temperature?

The Clausius inequality temperature is a thermodynamic concept that states that the temperature of a system cannot spontaneously decrease while it is in contact with a reservoir of constant temperature. In simpler terms, it means that heat will always flow from a warmer object to a cooler object, never the other way around.

2. How is the Clausius inequality temperature related to the Second Law of Thermodynamics?

The Clausius inequality temperature is closely related to the Second Law of Thermodynamics, which states that the total entropy of a closed system will always increase over time. The Clausius inequality temperature is a consequence of this law, as it explains why heat will always flow in a certain direction and not the other way around.

3. Can the Clausius inequality temperature be violated?

No, the Clausius inequality temperature cannot be violated. It is a fundamental principle of thermodynamics and has been proven through numerous experiments and observations. Any violation of this principle would go against the laws of physics.

4. How is the Clausius inequality temperature used in engineering and technology?

The Clausius inequality temperature is an important concept in engineering and technology, particularly in the design of heat engines and refrigeration systems. Engineers use this principle to ensure that their designs are efficient and comply with the laws of thermodynamics.

5. What is the difference between the Clausius inequality temperature and the Carnot efficiency?

The Clausius inequality temperature and the Carnot efficiency are two different concepts, but they are closely related. The Clausius inequality temperature explains why heat cannot spontaneously flow from a cooler object to a warmer object, while the Carnot efficiency is a measure of the maximum possible efficiency of a heat engine operating between two temperatures. In other words, the Clausius inequality temperature is a principle, while the Carnot efficiency is a mathematical concept that is derived from this principle.

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