Wow. Someone wants to know what time it is, and we proceed to provide instructions on building an atomic clock.
Getting back to the original question about understanding voltage. Voltage is the "prime mover" in an electrical system, just as a "push" is the prime mover in a mechanical system, or "pressure difference" is the prime mover in a fluid system. The voltage is a result of the potential energy that is stored in the battery. Packing the battery with electrons (by charging the battery) is similar in concept to pre-loading a spring by compressing (and holding) it, filling a tank up with water, or filling a party balloon with air.
You can think of voltage as an electrical pressure that can push existing electrons around in a closed circuit -- like when placing a resistor across the terminals of a battery. Normally such a circuit would benefit from the inclusion of a switch to make it easy to energize or de-energize the circuit at will. When the switch is closed, electrons will flow in the circuit from the negative terminal of the battery, through the resistor, and back into the positive terminal of the battery. When the switch is opened, the electron flow stops because the circuit path has been interrupted. The electrons don't go away -- they are still present in the molecular structure of the circuit -- they have just been isolated from the electrical pressure, or electro-motive force (EMF) provided by the battery.
I thought the billiard ball analogy was off to a good start, but then it never got developed in the context of our electrical circuit. When the switch is closed to complete the circuit, the battery will force electrons into the circuit (as fast as the circuit will allow) just like billiard balls being pushed through a tube (the circuit) that is already filled with billiard balls -- when a new billiard ball (electron) enters it bumps the next ball, which bumps the next, and the next, and so on until the one at the very end of the line is crowded out of the tube. In the case of electrons flowing in a circuit, that last electron goes back into the positive terminal of the battery. The continuous current flow (caused by the voltage delivered by the battery) is the result of electrons being bumped along from one atom to the the next in the circuit. The lower the value of circuit resistance, the higher the current flow.
As each electron flows out of the battery's negative terminal, the battery's capacity (and its voltage) is incrementally diminished just as a tank full of water would have its capacity (and pressure) incrementally diminished as water was allowed to flow out (drop by drop) of the bottom of the tank.
The reason that the voltage drop across the resistor is the same as the battery voltage is because the connecting circuit wires have, for all practical purposes (unless they are very, very long) no resistance. In the circuit described, the voltage drop across the resistor is a product of the resistance (in ohms) times the current flow (in amps), and has to be equal to the battery terminal voltage.
The amount of current flow the resistor allows will determine how long the battery will be able to push electrons through the circuit (just like the rate of flow out of the water tank will determine how long the every decreasing water pressure will cause water to flow out of the tank.