Conversion in equal volume CSTR and PFR

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Discussion Overview

The discussion revolves around determining which reaction order results in greater conversion in a Continuous Stirred Tank Reactor (CSTR) compared to a Plug Flow Reactor (PFR). The focus is on the mathematical relationships governing the conversions in both reactor types, particularly under varying reaction orders.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant is attempting to find an inequality that shows when the conversion in a CSTR is greater than that in a PFR, suggesting that this occurs when the reaction order n is less than 1.
  • Another participant suggests equating the mass balances of both reactors and then solving for the conversion in the PFR in terms of the conversion in the CSTR, recommending specific values for n to analyze.
  • A participant raises a concern about the case when n equals 1, questioning whether it leads to an indeterminate form.
  • In response, another participant notes that for n = 1, one should refer back to the original differential equation, indicating that the solution approaches a natural logarithmic form in this limit.

Areas of Agreement / Disagreement

Participants express differing views on the implications of reaction order, particularly at n = 1, and whether it leads to indeterminate forms. The discussion remains unresolved regarding the specific conditions under which XCSTR is greater than XPFR.

Contextual Notes

Participants have not fully resolved the mathematical steps involved in deriving the inequality or the implications of the reaction order on reactor performance.

Jaller1404
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Hello
I've been working on a problem that involves finding which reaction order gives a greater conversion for a CSTR over a PFR (Xcstr>Xpfr).
I was able to solve the mass balance for each reactor, finding:

upload_2017-12-5_1-25-15.png


and

upload_2017-12-5_1-28-13.png


Allowing us to equate them. This is where I've been stuck for a while now, how can I find an inequation that would get me which reaction order gives XCSTR>XPFR? It is known that this happen when n<1
 

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Set the two left hand sides equal, and then algebraically solve for Xpfr in terms of Xcstr. Then, for various values of n, plot a graph of Xpfr as a function of Xcstr. I suggest n = 0.5, 1, and 2.
 
Thanks for the tip, but wouldn't n=1 result in a 1/0 indetermination?
 
Jaller1404 said:
Thanks for the tip, but wouldn't n=1 result in a 1/0 indetermination?
For n = 1, you need to go back to the original differential equation. In the limit of n= 1, the solution approaches a natural log solution.
 
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