PFR model with n order reactions

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Discussion Overview

The discussion revolves around the design of a plug flow reactor (PFR) modeled as a series of five equal volume continuous stirred-tank reactors (CSTRs). Participants explore the implications of this modeling approach for a reactor design course, focusing on the incorporation of multiple reactions and the goal of achieving a specific conversion rate.

Discussion Character

  • Technical explanation
  • Homework-related
  • Exploratory

Main Points Raised

  • One participant describes the problem of designing a PFR with specific inlet conditions and multiple reactions, providing details on stoichiometric coefficients and rate laws.
  • Another participant confirms the approach of approximating the PFR as a series of five CSTRs.
  • A participant expresses understanding of the CSTR concept but seeks clarification on how to incorporate the reactions into the mass and mole balance equations.
  • A later reply questions whether the participant is unsure about solving a CSTR with chemical reactions, indicating a need for further clarification on this aspect.

Areas of Agreement / Disagreement

Participants generally agree on the modeling approach of using CSTRs to approximate the PFR, but there is uncertainty regarding the incorporation of reactions into the mass and mole balance equations. The discussion remains unresolved on how to proceed with this integration.

Contextual Notes

Participants have not fully detailed the assumptions underlying their approaches, nor have they resolved the mathematical steps necessary for incorporating reactions into the CSTR model.

Kevin Bacon
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This is a homework problem that was posted in another forum, so there is no template
I have this problem for my reactor design course and I need some help wrapping my head around it.

We have to design a plug flow reactor (PFR), which can be modeled as five equal volume CSTR's in series. The PFR has an inlet volumetric flow rate of ##q_{in}## which contains species ##A_i, i = 1...n## having concentration ##C_{Ai,in}## (also the whole PFR is operated at a constant temperature ##T_{ref}##).

The PFR is initially filled with solution containing species at concentration ##C_{Ai,0}##. The density of the inlet stream is constant at ##\rho##. There are ##m## reactions taking place within the PFR, each defined by the stoichemetric coefficients ##v_{i,j}## where ##i = 1...n, j = 1...m##.

Our goal is to design the smallest possible PFR to achieve steady state conversion of ##X_{A1} = 0.75##.

We are given a matrix of the stoichometric coefficients:
<br /> v = <br /> \begin{bmatrix}<br /> -a &amp; -b &amp; 0 &amp; d\\<br /> -a &amp; 0 &amp; 0 &amp; d\\<br /> a &amp; 0 &amp; -c &amp; -d\\<br /> 0 &amp; b &amp; c &amp; 0<br /> \end{bmatrix}<br />Basic rate laws:
<br /> r_{A1,1} = -kC_{A1}C_{A2}^2\\<br /> r_{A5,2} = kC_{A1}\\<br /> r_{A4,3} = -kC_{A4}^2\\<br /> r_{A3,4} = -kC_{A3}^2C_{A4}^2<br />
All k = 1, the inlet volumetric flow rate is given and a vector of five values for ##C_{Ai,in}## and ##C_{Ai,0}## are given. My approach so far is to create the net generation term being:

r = [-k*(c(1)*c(2)^2+c(1)^2+c(3)^2*c(4)^2-0.5*c(4)^2);
k*(c(1)-c(1)*c(2)^2);
k*(c(1)-c(4)^2);
k*(c(1)*c(2)^2-c(1)^2+c(3)^2*c(4)^2-0.5*c(4)^2)]

But do I take the CSTR approach or the PFR approach? A general idea would be very helpful. Thank you!
 
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You are approximating the PFR as a set of set of 5 CSTRs in s
 
Chestermiller said:
You are approximating the PFR as a set of set of 5 CSTRs in s

Yes, I understand this concept, I would have 5 CSTRS which means I'll have a mass and mole balance equation written around each, but how do I incorporate the reactions that are occurring?
 
Kevin Bacon said:
Yes, I understand this concept, I would have 5 CSTRS which means I'll have a mass and mole balance equation written around each, but how do I incorporate the reactions that are occurring?
Are you saying that you don't know how to solve a CSTR in which chemical reactions are occurring?

Chet
 

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