Could NMR be applied for other elements besides Hydrogen?

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SUMMARY

Nuclear Magnetic Resonance (NMR) can indeed be applied to elements other than Hydrogen, such as Phosphorus and Platinum, which are commonly used in various applications. The major challenge in multi-element NMR scanning lies in the requirement for nonzero nuclear spin and the natural abundance of isotopes, as seen with 1H, 13C, and 31P. While 1H is abundant, 13C is less so, making it necessary to consider isotopically enriched samples for effective analysis. Electron spin resonance is also mentioned as a related technique that focuses on electron spin states.

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  • Knowledge of isotopes and their natural abundances
  • Familiarity with electron spin resonance techniques
  • Basic concepts of spectroscopy in organic analysis
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xhtp2000
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Most books discribe NMR as a diagnotic technique for Hydrogen and its isotopes. Could Nuclear Magnetic Resonance Spectroscopy be applied for other elements with odd atomic number besides H? If so, what is the major challenge for a multi-element scanning?
 
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xhtp2000 said:
Most book discribe NMR as a diagnotic technique for Hydrogen and its isotopes. Could Nuclear Magnetic Resonance Spectroscopy be applied for other elements with odd atomic number besides H? If so, what is the major challenge for a multi-element scanning?

It definitely can and it is not an uncommon practice. Here's an example of NMR using Pt:

https://www.google.com/url?sa=t&rct...gikR_3oZQ&sig2=YGDlBc4U0DjdT9PWSXMnLA&cad=rja

Also note that electron spin resonance is a similar technique as NMR, but done onto the electron spin states.

Zz.
 
xhtp2000 said:
Could Nuclear Magnetic Resonance Spectroscopy be applied for other elements with odd atomic number besides H?
Certainly. Phosphorous is a commonly used nucleus also.
 
xhtp2000 said:
Most book discribe NMR as a diagnotic technique for Hydrogen and its isotopes.

Of four standard spectroscopic methods used in the organic analysis two are NMR techniques using different nuclei: H NMR and C-13 NMR. Two other are IR and MS.
 
ZapperZ said:
It definitely can and it is not an uncommon practice. Here's an example of NMR using Pt:

https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=2&ved=0ahUKEwj7uOC-94bKAhVCNSYKHakeDWEQFggkMAE&url=http://www.technology.matthey.com/pdf/pmr-v37-i1-017-023.pdf&usg=AFQjCNEBbxqmZZFm7m7oE-3LAgikR_3oZQ&sig2=YGDlBc4U0DjdT9PWSXMnLA&cad=rja

Also note that electron spin resonance is a similar technique as NMR, but done onto the electron spin states.

Zz.
Thank you so much for your answers guys! But what is the challenge to have a multi-elemental mapping using NMR, say, is it possible to have H, C13, P, etc.all elements with odd atomic numbers at the same time?
 
xhtp2000 said:
Thank you so much for your answers guys! But what is the challenge to have a multi-elemental mapping using NMR, say, is it possible to have H, C13, P, etc.all elements with odd atomic numbers at the same time?

What NMR requires is a nonzero nuclear spin - for example, 2H and 14N are often used for (quadrupolar) NMR studies in a variety of applications.

You need to examine the natural abundance of each isotope to see how the numbers pan out - for example, 1H is the vastly predominant stable isotope (> 99.9%), 13C is the vastly non-dominant stable isotope (~ 1%), and 31P is the only stable isotope (100%). However, it is possible to produce isotopically enriched samples to make doing experiments easier in that regard. So a naturally occurring chemical/biological/material sample here on Earth will be extremely rich in 1H, all 31P, but have a small amount of 13C. This may or may not be a problem, depending on what you want to do.
 

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