Cylohexanol stability of conformations

  • Thread starter Thread starter Chemist20
  • Start date Start date
  • Tags Tags
    Stability
AI Thread Summary
The discussion centers on the equilibrium between conformers of a molecule where the hydroxyl (OH) group can be positioned axially or equatorially. It is noted that in apolar solvents, the equilibrium favors the axial conformer less than in polar solvents. The role of entropy is mentioned as a potential factor influencing this equilibrium, with a suggestion to consider the impact of dipole moments in polar environments.
Chemist20
Messages
80
Reaction score
0
There is an equilibrium between the conformer in which OH is axial and the conformer in which OH is equatorial.

axial - equatorial

in apolar solvents, the equilibrium is less displaced to the right than in polar solvents.


Any ideas?

I think it has to do with entropy but not sure how...
 
Chemistry news on Phys.org
Think dipole moment.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
Back
Top