Deriving the Fermi Distribution: Fixed Particle Canonical Ensemble

  • Context: Graduate 
  • Thread starter Thread starter aaaa202
  • Start date Start date
  • Tags Tags
    Distribution Fermi
Click For Summary
SUMMARY

The discussion centers on the derivation of the Fermi distribution within the context of statistical mechanics, specifically contrasting the canonical ensemble with a fixed number of particles against the grand-canonical ensemble. It asserts that while many derivations utilize the grand-canonical ensemble due to its simplicity in calculating the partition function, notable exceptions exist, such as those found in Thirring's "Quantum Mathematical Physics: Atoms, Molecules and Large Systems," which employs the canonical ensemble. The conversation highlights the folk theorem suggesting equivalence of ensembles in the large N limit, while also acknowledging counter-examples that challenge this notion.

PREREQUISITES
  • Understanding of canonical and grand-canonical ensembles in statistical mechanics
  • Familiarity with the concept of chemical potential
  • Knowledge of partition functions and their calculations
  • Basic principles of quantum statistical mechanics
NEXT STEPS
  • Study the derivation of the Fermi distribution in Thirring's "Quantum Mathematical Physics: Atoms, Molecules and Large Systems"
  • Explore the implications of the folk theorem regarding ensemble equivalence in large N limits
  • Investigate the differences in calculating canonical versus grand-canonical partition functions
  • Learn about counter-examples to the equivalence of statistical ensembles
USEFUL FOR

Physicists, particularly those specializing in statistical mechanics and quantum mechanics, as well as students seeking a deeper understanding of the Fermi distribution and ensemble theory.

aaaa202
Messages
1,144
Reaction score
2
All derivations of the Fermidistribution uses a canonical ensemble with a chemical potential, which is the same as to say that the ensemble can exchange particles with a resevoir. But are the derivations still valid for the canonical ensemble with a fixed number of particles and why isn't this just used?
 
Physics news on Phys.org
The calculation of the grand-canonical partition function is much easier than calculation of the canonical one.
There is a folk theorem that all ensembles are equal in the large N limit, although there are counter-examples.
However, I strongly doubt that "All" derivations of the Fermi distribution use a grand-canonical ensemble.
E.g. I think Thirrings book "Quantum Mathematical Physics: Atoms, Molecules and Large Systems" contains a derivation using the canonical ensemble.
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
5K
  • · Replies 15 ·
Replies
15
Views
3K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 1 ·
Replies
1
Views
4K
  • · Replies 37 ·
2
Replies
37
Views
6K
  • · Replies 0 ·
Replies
0
Views
3K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 9 ·
Replies
9
Views
2K
  • · Replies 6 ·
Replies
6
Views
4K