Determining Thermal Coefficient of Binary Solvent Mixture

In summary, the conversation is about a science project involving the creation of silica aerogels using freeze-drying. The project requires experimentation with mixtures of solvents with low thermal expansion coefficients to avoid damaging the aerogel matrix. However, the question arises of how to determine the thermal expansion coefficient for a mixture of solvents, especially in their solid state. One suggestion is to find dV/dT using thermodynamic relations, but this method may be complex. The individual is seeking further explanation on this method.
  • #1
OptiPessimist
4
0
Hello,

Currently, I am working on a science project involving the creation of silica aerogels through the process of freeze-drying. As a result, i need to experiment with mixtures of solvents with low thermal expansion coefficients (so the crystallization of the solvents will not damage the aerogel matrix) However, i have hit a huge impediment.

While it is relatively simple to look up the thermal expansion coefficients for a given solvent,

how would one determine the thermal expansion coefficient for a mixture of solvents? (For example, the thermal expansion coef of a mixture of Tert Butanol and Propanol?)

Would the coefficient be nearly the same if the solvents were in solid state? (For they will be frozen, then sublimated)
 
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  • #2
i would suggest finding dV/dT using thermodynamic relations. might get a bit hairy
 
  • #3
Can you explain this method a bit more in depth?

Thanks
 
  • #4
bump...
 

Related to Determining Thermal Coefficient of Binary Solvent Mixture

1. What is the purpose of determining the thermal coefficient of a binary solvent mixture?

The thermal coefficient of a binary solvent mixture is a measure of how the mixture's temperature changes with respect to changes in its composition. This information is important in various scientific and industrial applications, such as designing efficient heat exchangers and predicting the behavior of solvents in chemical reactions.

2. How is the thermal coefficient of a binary solvent mixture determined?

The thermal coefficient of a binary solvent mixture can be determined experimentally by measuring the change in temperature of the mixture when small amounts of one solvent are added to another. This data can then be used to calculate the thermal coefficient using mathematical equations.

3. What factors can affect the thermal coefficient of a binary solvent mixture?

The thermal coefficient of a binary solvent mixture can be affected by various factors, including the types of solvents used, their proportions in the mixture, and the temperature and pressure at which the measurements are taken. Other factors such as impurities and the presence of other substances can also influence the thermal coefficient.

4. Can the thermal coefficient of a binary solvent mixture change over time?

Yes, the thermal coefficient of a binary solvent mixture can change over time. This can be due to changes in the composition of the mixture, variations in temperature and pressure, or the addition of impurities. It is important to regularly measure the thermal coefficient to account for any changes that may affect the behavior of the mixture.

5. How is the thermal coefficient of a binary solvent mixture used in practical applications?

The thermal coefficient of a binary solvent mixture is used in various practical applications, such as designing and optimizing heat transfer processes, predicting the solubility of solutes in the mixture, and determining the best conditions for chemical reactions. It is also a useful parameter for quality control and ensuring consistency in the behavior of solvent mixtures in industrial processes.

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