computerphys said:
Or asking that in another way, what is the observable operator associated to the charge of a particle?
Has the U(1) symmetry something to do with all that?
You wan't find an answer in quantum mechanics because there is no charge operator (e.g. for an electron in the Schrödinger equation). Charge is related to the charge density which itself is nothing else but the (square of the) wave function. So normalizing the wave function means that for the single particle Schrödinger equation you will always get "1e" for the charge.
You have to look at a theory which allows you to describe a charge operator and where you do not fix the charge of a quantum state in advance. In quantum field theory you can construct a charge operator and a corresponding conservation law. In QED this is related to the Gauss law of the U(1) symmetry and due to consistency (again coming from U(1)) you always get a constraint like
Q|phys> = 0
That means all physical states must have zero charge, otherwise the theory is inconsistent!
In QCD (or in general SU(N) gauge theories) the constraint is generalized to
Q
a|phys> = 0
where
a labels the different charges. Note that the charge operators generate an su(n) algebra like
[Q
a, Q
b] = if
abcQ
c
which is similar to the angular momentum algebra. So the condition
Q
a|phys> = 0
means that all physical states are charge-singulett states. If you look at angular momentum you know that if the z-comopnent is fixed, the x- and y-component are not. But that does not apply in our case, as in te singulett states
all components vanish; this is OK. The singulett state is rather special as it is the only state which is a simultaneous eigenstate of all charge operators!
Now if you look at charges
not related to local gauge symmetries there is no Gauss law and therefore no singulett condition. This applies e.g. to isospin. For isospin exactly the same SU(2) symmetry applies as for conventional spin: if there is a proton, which means
I
3|proton> = (+1/2)|proton>
where I
3 is the 3-component of the isospin, then the 1- and the 2-component are undefined
and you can derive an uncertainty relation for these components.