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No, that's not right. First, what are [itex]\sigma'_x[/itex], [itex]\sigma'_y[/itex], and [itex]\tau'_{xy}[/itex] equal to? Second, since you have to rotate by 90 degrees on Mohr's circle, that means [itex]2\theta=90^\circ[/itex], so [itex]\theta=45^\circ[/itex]. What do you suppose this 45 degrees corresponds to?