To calculate the potential energy of compressed air in a .81 Cu. Ft. cylinder at 80 Psi, it's essential to clarify the conditions of energy extraction, specifically whether the expansion is isothermal or adiabatic. The method of expansion significantly affects the energy calculations. Additionally, the discussion raises the possibility of considering energy in the context of a rupture scenario, akin to an explosion. Providing more context about the intended use or conditions would lead to a more accurate answer. Understanding these factors is crucial for determining the potential energy effectively.