Electron motion in the plum pudding model

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SUMMARY

The discussion focuses on the oscillation of an electron within the plum pudding model of the atom, characterized by a uniform positive charge distributed throughout a sphere of radius R. The user initially approached the problem using a 1D model, calculating forces from both sides of the electron's displacement and deriving an equation of motion (EOM) that did not yield expected simple harmonic motion. A suggestion to apply Gauss's Law clarified the situation, leading to a revised EOM of the form $$\ddot{r}+cr=0$$, indicating harmonic oscillation. The conversation emphasizes the importance of understanding model limitations and their implications on contemporary measurements.

PREREQUISITES
  • Understanding of the plum pudding model of atomic structure
  • Familiarity with Gauss's Law and its application in electrostatics
  • Basic knowledge of differential equations and equations of motion
  • Concept of simple harmonic motion and its characteristics
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  • Study the application of Gauss's Law in electrostatics to solidify understanding
  • Explore the implications of the plum pudding model on early atomic theory and its limitations
  • Investigate the derivation and solutions of simple harmonic motion equations
  • Examine contemporary measurements related to atomic models and their accuracy
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Students of physics, particularly those studying atomic models, educators explaining electrostatics, and researchers interested in the historical context of atomic theory.

jamie.j1989
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Hi, I am trying to work out how the electron would oscillate about a mean position in the plum pudding model.

Plum pudding model;
-1 electron atom.
-Positive charge of ##+e## distributed evenly about the volume of the atom of radius ##R##.
-Electron (charge ##-e##) is free to move within the sphere.

My first attempt at this is to take it as a 1D problem with a positive line charge of density ##l=\frac{e}{2R}##. When perturbing the electron along the left side of this line of displacement ##-r##, where the origin is at the centre of the sphere, I evaluated the force on the electron from the two sides to be,

$$F_L=-\frac{e^2}{8\pi \epsilon_0 R}\int_{-r}^{-R}r^{-2}dr=-\alpha\left(R^{-1}-r^{-1}\right)$$.

With ##\alpha=\frac{e^2}{8\pi \epsilon_0 R}##, ##F_L## is the force from the left side charge distribution. And for the right side,

$$F_R=-\frac{e^2}{8\pi \epsilon_0 R}\int_{-r}^{R}r^{-2}dr=\alpha\left(R^{-1}+r^{-1}\right)$$.

Where for both I have taken infinitesimal force ##dF##, to be,

$$dF=-\frac{edq}{4\pi \epsilon_0 r^2}$$.

Where ##dq=ldr##. So the net force on the electron (##F_L+F_R##) will be able to give us the equation of motion for the electron, which is

$$\ddot{r}-\frac{\alpha}{m}\frac{1}{r}=0$$.

I'm not sure why but I feel like this is wrong, I would expect the solution to the EOM to be simple harmonic but this doesn't seem to give that. Can anyone clarify whether this is an issue with the 1D approximation, or with the workings? Thanks.
 
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Hi, I am trying to work out how the electron would oscillate about a mean position in the plum pudding model.
Um... why?
 
Why not? It's good practice to see where a model breaks down. To what degree does the oscillation of the electron and its emitted radiation from the acceleration about the equilibrium position agree with measured values. Again, it's good practice to know the things that are wrong and why, rather than just what's correct.
 
Are you familiar with Gauss's Law? If you assume the "pudding" is a sphere with uniform (positive) charge density, you can use Gauss's Law to show that the electric field inside the sphere, a distance r from the center, is proportional to r. The direction of the field is away from the center. Therefore the force on an electron at distance r from the center is also proportional to r, and directed towards the center.
 
Ahh, didn't even think to use Gauss's law, have got down to an EOM of what I expected

$$\ddot{r}+cr=0$$

Thanks
 
There were a lot of ways to respond. In order to best answer your questions, it is useful to know what your intended purpose/motivation is.

You have posted a radial eom, orbital motion forms part of Thompson's model too.
https://en.m.wikipedia.org/wiki/Plum_pudding_model

Note: it is usually more useful to examine limitations to a model with such a serious flaw (wildly incorrect charge distribution) if its impact of contemporary measuremrnts is examined. ie it was used in early attempts to determine the bohr radius for hydrogen.
 

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