Electron Paramagnetic Resonance Spectroscopy

Ravi Deshmukh
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I am a chemistry student and would like to know how to identify the g(parallell) and g(perpendicular peaks in the ESR spectra of copper(II) complexes.
 
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Your best bet is to go find a textbook on physical methods in inorganic chemistry.

Having said that, there is a very brief introduction to this very topic here by Andrew Barron (Rice University). If you need dramatically more information - including on the technique itself - refer to the first sentence of this post. It really helps to have spectral data in front of you to look at, scribble on, and annotate to begin the learning process, I found.
 

Thread 'Instantaneous dipole moment and orbitals'

Hi. I have got question as in title. How can idea of instantaneous dipole moment for atoms like, for example hydrogen be consistent with idea of orbitals? At my level of knowledge London dispersion forces are derived taking into account Bohr model of atom. But we know today that this model is not correct. If it would be correct I understand that at each time electron is at some point at radius at some angle and there is dipole moment at this time from nucleus to electron at orbit. But how...
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