Energy of Conduction and Valence Band in Opposing Directions

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Discussion Overview

The discussion revolves around the interpretation of the energy bands in an E-k diagram, specifically addressing why the conduction band curves upward while the valence band curves downward. Participants explore concepts related to solid-state physics, including the representation of energy bands and the behavior of electrons and holes.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant notes that the upward and downward curves in the E-k diagram are a result of the representation used, suggesting the use of reduced-zone or extended-zone schemes.
  • Another participant introduces the idea of holes as having negative mass, contributing to the conceptual understanding of energy states.
  • It is mentioned that the upward and downward directions in the diagram indicate the highest occupied energy state of the valence band and the lowest unoccupied state of the conduction band, respectively.
  • A participant elaborates on the complexity of the E-k diagram, indicating that it can have multiple vertical gaps and that the diagram referenced focuses on a specific region where electronic states are filled or empty.
  • There is a discussion about the parabolic shape of the bands, which relates to the effective mass of electrons and holes.

Areas of Agreement / Disagreement

Participants express various interpretations of the E-k diagram, and while there are informative contributions, no consensus is reached regarding the implications of the upward and downward curves or the nature of the energy states.

Contextual Notes

The discussion highlights the limitations of the E-k diagram representation, including the omission of broader structural features and the focus on a specific point of interest in semiconductors.

Athenian
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TL;DR
In an ##E(k)## diagram where one can think ##k## as being the momentum and ##E## as the energy, why are the diagram's conduction and valence band in opposite directions?
Recently, I have been studying some solid-state physics and I came across this ##E-k## diagram online. Here's an image for reference to what I am referring to: [https://www.google.com/search?sourc...6BAgJEAE&biw=767&bih=712#imgrc=YnRTyhlOuJmRaM].

In short, I was curious why would the conductor band curve upward whereas the valence band curves downward in an electronic band structure (i.e. in the ##E-k## diagram).

In addition, if anybody knows any good solid-state physics sources I can refer to for this question (or similar topics to read and study), I would definitely like to hear about it.

Thanks a lot!
 
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The impression you have is only because to the type of representation used. Energy bands can be represented in the reduced-zone scheme or in the extended-zone scheme. Have a look at Fig. 5 in Tsymbal's
Energy bands - Rutgers Physics
 
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Think of a hole as a negative mass
 
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I think it doesn't mean that upward or downward direction. It shows the highest occupied energy state of the valance band and lowest unoccupied state of the condiction band
 
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Dr Transport said:
Think of a hole as a negative mass

To my mind, when thinking in terms of electrons and holes, one has to consider the direction of the energy axis.

"Both electrons and holes tend to seek their lowest energy positions. Electrons tend to fall in the energy band diagram. Holes float up like bubbles in water."
From caption of Fig. 1-14 in
Electrons and Holes in Semiconductors
 
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1. The E-k diagram is actually extended and complicated, there could be several areas where there are vertical gaps. The diagram you linked is ignoring all of that and focusing on one part, the specific gap where the electronic states below the gap are filled and the states above the gap are empty (at low temps). And again, it is ignoring the whole left-right structure as well, which could have an undulating shape for both the conduction and valence bands, and focusing on the single point of closest approach. So that's the reason it has that >< shape, it's focusing on the point of closest approach.

The reason for focusing on that point is because in a semiconductor, that one point is where most of the interesting stuff happens. The chance to jump the gap reduces exponentially with the size of the gap, so pretty much all of the electron promotion/electron falling happens right there, for those values of ##\Delta E## and k.

2. Notice they're also usually drawn with a sort of parabolic shape. This is because that shape determines the electron and hole effective mass, and it's usually close to parabolic.
 
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Thank you everybody for the informative comments! This was incredibly helpful when attempting to understand ##E(k)## diagram.
 
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