In reversible processes, the change in entropy (∆S) for the system is zero, indicating that the system can return to its original state without any net change. However, for a reversible isothermal process, the change in entropy is quantified by the equation ∆S(system) = nRln(Vf/Vi), where Vf and Vi represent the final and initial volumes, respectively. This highlights that while the system undergoes a change, the total entropy change (∆S(total)) for both the system and surroundings remains zero, as expressed by the equation ∆S(total) = ∆S(surroundings) + ∆S(system). This balance is crucial in understanding thermodynamic processes and the nature of reversibility.