Evaporation: Impact of Pressure & Other Factors

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    Evaporation
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Homework Help Overview

The discussion revolves around the factors affecting the rate of evaporation of water, particularly in relation to pressure changes, such as when water is placed under partial vacuum. Participants explore how atmospheric pressure influences evaporation and the implications of changing conditions.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants question the relationship between pressure and evaporation, considering how reduced pressure might affect the rate of evaporation. Some express uncertainty about the role of partial pressure of water vapor and the distinction between evaporation and boiling.

Discussion Status

The discussion is active, with various interpretations being explored. Some participants provide insights into the mechanisms of evaporation under different pressure conditions, while others express the need for clearer definitions and understanding of the concepts involved.

Contextual Notes

There are mentions of incomplete problem statements and the need for additional context regarding the system's volume and conditions. The discussion also highlights the importance of distinguishing between different types of pressures affecting evaporation.

Anshuman Bajpai
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1. Water evaporates under atmospheric pressure. Without changing the temperature , the same water is placed under partial vacuum . The rate of evaporation will
a] increase
b] decrease
c] drop to zero
d] remain unaffected


2. No eqns reqd3. The evaporation is a slow process that can occur at any temp. Other factors affecting evaporation are - Windspeed, Humidity, Surface Area of liquid .
 
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Your attempt does not really try to answer the question. There is a single correct answer among the listed ones.
 
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what happens to the temperature at which water boils as you move up a mountain and the air pressure decreases?
 
You can think of liquid water as bunch of H2O molecules stacked all together and aren't allowed to freely move around, when you heat them they gain some energy and dance around, this is when you see water boil and vaporate, but even at a room temperature some of the molecules make it through and flee thus turning into gaz(evaporate), pressure is one of the most important reason that these molecules were stacked in the first place because it presses them, in partial vacuum pressure goes down, so what might happen then ?
 
Noctisdark said:
You can think of liquid water as bunch of H2O molecules stacked all together and aren't allowed to freely move around, when you heat them they gain some energy and dance around, this is when you see water boil and vaporate, but even at a room temperature some of the molecules make it through and flee thus turning into gaz(evaporate), pressure is one of the most important reason that these molecules were stacked in the first place because it presses them, in partial vacuum pressure goes down, so what might happen then ?
Not my area of expertise (if there is such), but I don't think it's as simple as that. Isn't it the partial pressure of the water vapour that's critical? If I understand correctly, the answer could be different if the air is completely dry. To put it another way, don't confuse evaporation with boiling.
 
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haruspex said:
Not my area of expertise (if there is such), but I don't think it's as simple as that. Isn't it the partial pressure of the water vapour that's critical? If I understand correctly, the answer could be different if the air is completely dry. To put it another way, don't confuse evaporation with boiling.
Yes. I agree also. The equilibrium vapor pressure of water does not change significantly with air pressure in the system. The air in the gas phase above the water provides resistance to water diffusion away from the interface. If you lower the air partial pressure by lowering the total pressure, water in the gas phase can diffuse more easily away from the interface. This results in increased evaporation rate.

Chet
 
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... or, remain unchanged if the volume of the system remains unchanged.
I'd call the problem statement "incomplete."
 
Noctisdark said:
This is an introductory text, but I will worka lot of thing http://www.chem4kids.com/files/matter_evap.html , Good luck !
[Yes, Evaporation rate will increase, molecules can easily flee ]
Again, that text does not discriminate clearly between the pressure of the gas and the partial pressure of the vapour. As Chet described, the mechanism is quite subtle.
 

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