Find an Expression for the Helmholtz free energy

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Homework Help Overview

The problem involves finding an expression for the Helmholtz free energy as a function of temperature, T, based on a system with two energy states: one at energy 0 and another at energy ε.

Discussion Character

  • Exploratory, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to derive the Helmholtz free energy using the partition function Z and expresses concern about the correctness of their approach. Some participants question the necessity of substituting β with its definition in terms of temperature, while others emphasize the importance of consistency in notation.

Discussion Status

The discussion is ongoing, with participants exploring the implications of using different notations and questioning the need for substitutions. There is no explicit consensus on the approach to take, but guidance on maintaining consistency in notation has been provided.

Contextual Notes

Participants are discussing the implications of using both β and kT in the equations, which may indicate a need for clarity in the definitions being used.

conorod
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Homework Statement


I am attempting the problem below, I might have the correct answer but would appreciate if someone could confirm this (or tell me where I'm going wrong).
Consider a statement having 2 states, one at energy 0 and one at energy ε. Find an expression for the Helmholtz free energy as a function of the temperature, T.


Homework Equations


F = -kBT log Z

Z = Ʃ e-βEr


The Attempt at a Solution



Z = e-β.0 + e-β.ε
Z = 1 + e-β.ε

F = -kBT ln(1 + e-β.ε)
 
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Isn't β =1/(kBT)? Shouldn't you substitute that into your equation?
 
I'm not sure - is that necessary? Or is it OK to just use β?
 
Well you want to at least be consistent. In your final equation, you use both beta and kT.
 

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