If $f(x)=f(y)$ then $\log(x+1) =\pm \log(y+1)$. Apart from the obvious solution $y=x$, that has the solution $y+1 = \dfrac1{x+1}$. Given that $f(a) = f\left(-\dfrac{b+1}{b+2}\right)$, it follows that either $-\dfrac{b+1}{b+2}=a$ or $-\dfrac{b+1}{b+2}+1 = \dfrac1{a+1}$. The second of those two possibilities leads to solakis's suggestion $a=0$, $b=-1$, which would be a solution apart from the fact that it does not satisfy the condition $b>a$.
So we have to look at the possibility $a = - \dfrac{b+1}{b+2}$. The equation $f(10a+6b+21) = 4\log2$ then says that $\log\left(-\tfrac{10(b+1)}{b+2} + 6b + 22\right) = \pm\log16$. Therefore $-\tfrac{10(b+1)}{b+2} + 6b + 22 = 16 $ or $\tfrac1{16}$.
If $-\tfrac{10(b+1)}{b+2} + 6b + 22 = 16 $ then $(b+1)\bigl(-10+ 6(b+2)\bigl) = 0$. That again has the unwanted solution $b=-1$, but it also has the solution $b+2 = \frac{10}6$, from which $b=-\frac13$. The corresponding value of $a$ is $-\frac25$.
(There was also the possibility that possibility that the equation $-\tfrac{10(b+1)}{b+2} + 6b + 22 = \tfrac1{16} $ might lead to a solution. But in fact that equation has no real solutions.) So the solution is $\boxed{a=-\dfrac25,\ b=-\dfrac13}$.