Finding pH of solution knowing E°....

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To determine the minimum pH of a solution where a nickel bar does not produce hydrogen, the electrochemical reaction involving Ni2+/Ni with E° = -0.25V is analyzed. The relevant reaction is 2H+ + Ni → Ni2+ + H2. Using the Nernst equation, it is established that the reaction will not occur if the potential is less than zero. The calculations indicate that for hydrogen not to be produced, the pH must be greater than 8.46. Thus, maintaining a pH above this threshold prevents hydrogen generation in the solution.
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Homework Statement


The pair Ni2+/Ni has E°=-0.25V. Find the minimum pH of the sulution so that a nickel bar immersed in it, doesn't produce hydrogen.

Homework Equations


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The Attempt at a Solution


This problem doesn't make any sense to me. Maybe there is a cell in which the following reaction occurs:
2H+ + Ni ---> Ni2+ + H2

I thought I could use something like the Nernts equation but I don't know [Ni2+].

I need some guidance. Thank you.
 
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You don't need concentration of Ni2+ if the potential is given. Actually even the identity of the metal doesn't matter.
 
Ok, this is what I get:

-0.0591/2 * log( 1/[H+]2 ) + 0.25 < 0 [the reaction does not occur and hydrogen is not produced]
pH > 8.46
 
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