Forbidden gap in semiconductors.

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SUMMARY

The discussion centers on the concept of the forbidden gap in semiconductors, specifically addressing the apparent contradiction of the Fermi level existing within this gap. It is established that while the forbidden gap separates the conduction band and valence band, the Fermi level can still be present due to the influence of doping, which introduces additional energy levels. The intrinsic Fermi level (Ei) is defined as the position of the Fermi level in the absence of doping, and its position relative to the conduction (EC) and valence (EV) bands is crucial for understanding electron and hole densities in semiconductors.

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  • Understanding of semiconductor physics
  • Knowledge of energy bands: conduction band and valence band
  • Familiarity with the concept of doping in semiconductors
  • Basic grasp of Fermi level and intrinsic Fermi level (Ei)
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  • Study the effects of doping on semiconductor properties
  • Learn about the mathematical formulation of Fermi level positioning
  • Explore the implications of thermodynamic equilibrium in semiconductors
  • Investigate the role of temperature on electron and hole densities in semiconductors
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Students and professionals in physics and engineering, particularly those focused on semiconductor technology, electronic engineering, and materials science.

savi
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in books we have read that there lies a forbidden gap between conduction band and valence band. and electrons can not exist in this gap i.e. probability of electron being found in this region should be zero.
BUT the fermi level,which has 50% prabality to contain an electron is found in forbidden gap for a semi conductor generally. how can this be possible if no electron can exist in forbidden gap?
 
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savi said:
in books we have read that there lies a forbidden gap between conduction band and valence band. and electrons can not exist in this gap i.e. probability of electron being found in this region should be zero.
BUT the fermi level,which has 50% prabality to contain an electron is found in forbidden gap for a semi conductor generally. how can this be possible if no electron can exist in forbidden gap?
When atoms are brought close together, as in a solid, the electrons come under the influence of forces from other atoms, where the energy level merges into bands of energy levels. There are two distinct energy bands in which electrons could exist: the valence band and the conduction band . Separating these two bands is an energy gap , termed the forbidden gap, in which electrons cannot normally exist.

The central task of basic semiconductor physics is to establish formulas for the position of the Fermi level EF relative to the energy levels EC and EV (the level of the bottom of the conduction band and the top of the valence band), taking into account the effects of "doping". Doping introduces additional electron energy levels into the band gap, that may or may not be populated by electrons, dependent on circumstances and temperature, and causes the Fermi level EF to shift from the energy level (relative to the band structure) that it would have had in the absence of doping. This energy level that the Fermi level has in the absence of doping is called the intrinsic Fermi level (or "intrinsic level") and is usually denoted by the symbol Ei.

The theory of semiconductor physics is constructed in such a fashion that – in a situation of complete thermodynamic equilibrium – the position of the Fermi level, relative to the band structure, determines both the density of electrons and the density of holes.
Avinash Singh
Jr. YSR (ISCA)
Mech. Eng.
KIIT Univesity
BBSR
 

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