Applying a force at the center of mass results in pure translation without rotation. This is because torque, defined as the cross product of the position vector from the center of mass to the force application point and the force itself, becomes zero when the position vector is zero or parallel to the force. Consequently, no rotational force is generated. The mathematical proof hinges on the relationship between force, torque, and the center of mass. Understanding this principle is crucial in mechanics and dynamics.