Originally posted by rtharbaugh1
When you say that two electrons are made to collide, I wonder how this is done. How close together must the electrons be to collide? Does an electron have a radius?
in principle, any electrons can interact, although in practice they have to be very close to have a noticable effect.
classically, you know that the electric field from the point particle is just E=e
2/r
2. this means that the electric field fills all space.
this formula neglects quantum effects, so its not valid for high energy electrons, but the point is that "collide" just means get close enough to repel each other electrically.
as far as we can tell, the electron has no radius.
Do we know what the spin of the electrons was before the collision?
usually the electron beam is unpolarized, meaning it is an equal mixture of all spin states.
in that case, we have a formula for the interaction that depends on the spin, and we average over all spin states.
Does it make any difference if the electrons both have the same spin to start out with or if they start out with different spins?
yes, it makes a difference. but as i said above, usually the beams are unpolarized, and we average over spin states.
Can spin be related to one of our three spatial dimensions?
in a sense. certainly, spin is a 3 vector, which means that it points in some spatial direction.
but i am referring here to the spin operator, which is not the same thing as the "value of the spin" of the electron in question. since the various components of spin are noncommuting observables, it doesn t make sense to talk about the spin of the electron having a direction in 3 dimensional space. the best you can do is specify one component of that vector. that is why we refer to them as spin up and spin down. the up and down refer to one component of the spin, and the other components of the spin are not in an eigenstate.
Is there any way to separate spin + electrons from spin- electrons?
sure: the Stern-Gerlach apparatus. this is, in fact, how spin was first discovered. basically, just run the electrons through a magnetic field. since magnetic field couples to spin, it will interact differently with spin up and spin down, and separate them into two separate beams.
in this way, you can turn an unpolarized beam into a polarized one.
If I had an apparatus to measure the spin of a stream of spin+ electrons (assuming such a stream can be created) and I inverted the apparatus, would the apparatus indicate that the electrons were now spin-?
yes. all you have done is change coordinates, really.
How is the spin of an electron measured? Does the measurement process affect the spin state?
by its interaction with the magnetic field, that s one way.
and yes, it does affect the spin. before the measurement, the electrons were not in an eigenstate, and afterwards, they are.
Does this mean that a chemical bond will not form between, say, Na+ and Cl-, unless the two atoms have electrons of opposite spin? Wouldn't this mean that two such atoms brought sufficiently close together would only form a bond half the time? Can we manipulate single atoms of sodium and chlorine to test this idea? Has it been done?
hmm... it s a little more complicated than that. the electron in the Cl ion and the electron in the Na atom both have wavefunctions. when you put the two atoms together, you get a few possible combinations of wavefunctions, one which is symmetric, and one which is antisymmetric. Pauli s exclusion principle allows the two electrons to have the same spin if they are in the antisymmetric combination of wavefunctions, and if they have opposite spins, they must go into the symmetric wavefuntion.
one of the combinations will have lower energy than the other, and the system can combine in whichever way is allowed, and then decay to the lower energy state.
in the end, no matter what the spin of the two atoms is, you can always make the bond.
but your idea that the reaction will only go forward half the time is not completely wrong. i would say that the reaction is slightly more favorable half the time (when the spins are aligned correctly). however, the energy difference between the spin states is so small compared to the energy released by the reaction, that in either case, the reaction will procede, and probably the difference in rates would be completely unmeasurable