Swapnil
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When you throw a golf ball on the ground it bounces back up slightly after hitting the ground. What kind of force is responsible for this effect?
It seems that the L-J potential doesn't have any theoretical justificaion but it is just an experimental fact. Either way, it is only a potential and it is not even associated with a force! Then how is the L-J potential a type of electromagnetic FORCE?quasar987 said:But to answer your specific question on the nature of the force itself, it is as you would have guessed electromagnetic ... More precisely, the electromagnetic force btw molecules is not coulombian since the molecules are essentially neutral. Rather, the potential is of the Van der Waals type, such as the Liénard-Jones potential:
http://en.wikipedia.org/wiki/Lennard-Jones_potential
It is a potential caracterized by a very strong repulsion ~1/r^12 (!) at close distances and a (quickly fading) attraction past a distance of ~4 Anstrom to the molecule.
quasar987 said:To every potential V(x), there is an associated force F(x)=-\frac{dV}{dx}. When one says "potential", you should hear "force". When looking at the graph of a potential function, you should recognize in the regions of steep slopes a strong force, repulsive when the curve is decreasing, attractive when the curve is increasing.