1. The problem statement, all variables and given/known data Knowing that the wave function of the hydrogen atom is proportional to e-r/a0, estimate how t depends on the proton proton separation d. I need just to make a drawing of the integrand and make a reasonal approximation using my intuition (no numerical methods allowed to calculat the integral.) 2. Relevant equations t is the overlap tunneling matrix element, with t= - <L|VL|R> with L= 1s- wavefunction centered on the left proton = psi1s(L-r) R= 1s- wavefunction centered on the right proton = psi1s(R-r) ( L or R is the position of the left or right proton, r is the position of the electron) VL= the attractive potential of the left proton on the electron= V(L-r) 3. The attempt at a solution I just want to know whether my solution would be sufficient to this question, or whether I would need to do some more reasoning/ calculus/ plotting of functions. t= - <e-(L-r)/a0 | -e2/ (4*pi*e0*(L-r)) | e-(R-r)/a0> = e2/ (4*pi*e0) * (integral taken over dr) (1/(L-r)) * e-(L-r)/a0 -(R-r)/a0 as d= | L-R | R= L-d so plugging that into the above equation for t gives: t= = e2/ (4*pi*e0) * (integral taken over dr) (1/(L-r)) * e(-L+r)/a0 (-L+d +r)/a0> When d decreases, the exponent of e gets larger , therefore t gets larger too. When d increases, the exponent of e gets smaller, therefore t gets smaller too. Is this it? I mean, the question said I needed to draw something and use my intuition, which I obviously did not do to solve this problem, this is just reasoning. What do I need to add? E.g. do I need to be more specific on the dependency other than 'getting bigger/ getting smaller', but say 'it behaves like an exponentially increasing function/ like a parabolic function etc'? Thanks in advance! I really appreciate your help!