Basic_Physics is suggesting that you shouldn't really rely on R being constant or the same at all temperatures. Would have been better to measure V as well as I and use energy = VIt rather than I2Rt.
There are lots of ways to make mistakes when doing calorimetry. Sorry if any of my suggestions are too obvious an error for you to have made.
The equation..
Q = (mwcw+mccc+mhch)(Tf-Ti)
assumes the water, calorimiter and heater all undergo the same temperature rise Tf-Ti. Were any precautions taken/necessary to ensure that was the case? Was enough time allowed both at the start and the end for temperatures to stabilize ? Was second run rushed because lab session ending?
Was Tf anywhere near boiling point? Any steam emerging?
Was new cold water used for the second run? Are you sure the mass of water used was same for both runs or if different was that included in the calculation?
How big was Tf-Ti? More than a few degrees? Accuracy of thermometer? Thermometer battery Ok?