Heat required at constant pressure

In summary, the conversation discusses how much heat energy is required to raise the temperature of a gaseous mixture of 1 gm of hydrogen and 1 gm of helium from 0 degree C to 100 degree C at constant pressure. The equation used is Heat required = nC(p)dT, and the specific heat values for each component are calculated using the ratio of specific heats at constant volume and pressure. The final answer is 53200 Joules or 12666 Calories, and it is noted that the previous answer of 709.7 J/mole-K is incorrect due to a calculation error.
  • #1
Amith2006
427
2

Homework Statement


1) How much heat energy must be added to the gaseous mixture consisting of 1 gm of Hydrogen and 1 gm of Helium to raise its temperature from 0 degree C to 100 degree C
at constant pressure? Given that g1=1.41, g2=1.67



Homework Equations



Heat required = nC(p)dT

The Attempt at a Solution




Heat energy in Joules:

Let C(p1), C(p2) and C(p) be the specific heat of Hydrogen, Helium and the mixture at constant pressure respectively. Let g1,g2 and g be the ratio of the specific heats at constant volume and pressure for Hydrogen, Helium and the mixture respectively. Here I have taken the value of the universal Gas constant[R] = 8.314 Joule/mole-K
C(p1) = (g1 x R)/(g1 -1)
= 28.59 J/mole-K
C(p2) = (g2 x R)/(g2-1)
= 20 .72 J/mole-K
C(p) = {(n1 x C(p1)) + (n2 x C(p2))}/(n1 + n2)
= 709.7 J/mole-K
Let n1,n2 and n be the number of moles of Hydrogen, Helium and the mixture respectively.
n1 = 0.5 moles
n2 = 0.25 moles
n = 0.75 moles
Heat required = nC(p)dT
= 53200 Joules = 12666 Calories

Heat energy in Calories:

Here I have taken the value of the universal Gas constant[R] = 1.99 Calorie/mole-K
Heat required = 466 Calories
Why do I get 2 different answers just because of change in units of R?
 
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  • #2
Because your C(p) = 709.7 can't possibly be right. If the components have Cp of 28.59 and 20.72, the mixture must have Cp in between those values.

The equation looks OK, so I guess you hit the wrong buttons on your calculator.
 
  • #3
U r right. What am I doing??Thanks.
 

1. What is the definition of heat required at constant pressure?

Heat required at constant pressure refers to the amount of thermal energy needed to raise the temperature of a substance while keeping the pressure constant.

2. How is heat required at constant pressure different from heat required at constant volume?

The main difference between heat required at constant pressure and heat required at constant volume is that at constant pressure, the volume of the substance can change, while at constant volume, the volume remains constant.

3. How is heat required at constant pressure calculated?

The heat required at constant pressure can be calculated using the formula Q = m * CP * deltaT, where Q is the heat required, m is the mass of the substance, CP is the specific heat capacity at constant pressure, and deltaT is the change in temperature.

4. What factors affect the amount of heat required at constant pressure?

The amount of heat required at constant pressure is affected by the mass of the substance, its specific heat capacity, and the change in temperature. Other factors such as the type of substance and its physical state can also play a role.

5. Why is heat required at constant pressure important in scientific experiments and processes?

Heat required at constant pressure is important because it allows us to control the temperature of a substance while keeping the pressure constant. This is crucial in many scientific experiments and processes, such as in chemical reactions, where the temperature and pressure need to be carefully controlled for accurate results.

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