leright said:
that is the energy operator. the hamiltonian can take the form of a time derivative or a second spatial derivative...I think.
When |\psi(t)\rangle, a state vector that is a function of time, satisfies the Schrödinger's equation
<br />
i\hbar\partial_t|\psi(t)\rangle = H|\psi(t)\rangle,<br />
then, by definition, the operators i\hbar\partial_t and H will have the same effect on any such vector, but in general these are different operators. They must be of course, since if they were the same, the SE would have no content about the time evolution of the state!
In other words, if |\xi(t)\rangle is some arbitrary parametrization of a path in the state space, then you can have
<br />
i\hbar\partial_t|\xi(t)\rangle \neq H|\xi(t)\rangle.<br />
So, they are different operators, and it is correct to write
<br />
i\hbar\partial_t \neq H.<br />