An intuitive explanation for why holomorphic implies conformal can be seen from the power series expansion of a function.
A complex function, differentiable at 0 can be expressed as a power series in some finite circle around the origin: f(z)=f(0)+f'(0)z+f''(0)\frac{z^2}{2!}+\cdots. Sufficiently near the origin, we can ignore the higher powers of z. So this is approximately just a (affine) linear function, as long as f'(0)\neq0: a multiplication by a fixed complex number, which is just a rotation (by the argument) and dilation (by the modulus), followed by a translation. This is clearly conformal (and conversely every conformal transformation must locally look like this).
On the other hand, if f'(0) vanishes, the higher order terms are dominant so there is an additional power of z. So, for example, if the first nonvanishing derivative is the second, the function locally looks like z\mapsto z^2 (followed by rotation, dilation & translation). You just have to look at the polar form to see that this doubles angles at the origin so it isn't conformal.
Locally, any complex differentiable function looks like a power, so to understand the local behaviour you need only understand z, z2, z3 etc. This is all just heuristic, but hopefully it will help to understand why it works.