Light dependent resistors (photoresistors) operate by utilizing photons to excite electrons in semiconductor materials like silicon. When a photon with sufficient energy strikes the material, it frees an electron, allowing it to move and conduct electricity. Increased light exposure results in more free electrons, leading to higher current flow and lower resistance. Commonly, these resistors are made from cadmium sulfide (CdS). Understanding this mechanism is crucial for applications in light sensing and automation.