How Do We Calculate Different Average Diameters of Colloids?

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To calculate the average diameters of colloids, two types are discussed: surface average and volume average. The surface average diameter can be calculated using the formula involving the total surface area and the number of particles. The volume average diameter requires knowledge of the volume percentage of the dispersion, which in this case is 60% water. The discussion emphasizes using the total surface area and the number of particles to derive the surface area of a single particle, which aids in calculating the average diameter. Understanding these calculations is crucial for characterizing colloidal dispersions effectively.
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A dispersion of spherical polymer particles contains Np = 4•1013 particles/dm3. The total surface of the particles in 1 dm3 is Asp = 820 m2.

a) What kind of average diameter can we calculate. Calculate this average diameter.

b) If we know that the dispersion contains 60 vol% water, we can calculate another type of average diameter. Which? Find it!


a) Surface average.

\bar{d_s} = \sqrt{\frac{\Sigma n_i d_i^2}{\Sigma n_i}}

b) Volume average.

\bar{d_s} = \sqrt{\frac{\Sigma n_i d_i^3}{\Sigma n_i}}

I don't know how to incorporate the data into the formulas.
 
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Can't you just work it out by taking the surface area of a sphere and working back to get the radius?

You know the total surface area of the total particles in 1 litre, and you know how many particles there are in 1 litre, so from that you can work out the surface area of 1 particle.
 
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