How does (AlK(SO4)2•12H2O) balance?

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The discussion focuses on the dissociation of aluminum potassium sulfate dodecahydrate (AlK(SO4)2•12H2O) in water, clarifying that it separates into ions Al3+, K+, and SO4^2-. The participants address the misconception of forming aluminum hydroxide (AlOH) as a product, emphasizing that it is not a direct result of dissolution. The conversation also touches on the complexity of cation hydrolysis, particularly with Al3+, which can form various complexes in solution. Participants suggest that while understanding these reactions is important, detailed knowledge of all equilibrium constants is not necessary for those new to the topic. Overall, the thread provides insights into the basic principles of dissolution and ion dissociation in aqueous solutions.
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So like say you have (AlK(SO4)2•12H2O)
And then how does the reaction go?

Is it like (AlK(SO4)2•12H2O) -> AlOH + H2SO4 or something like this?

Was also wondering how like
(NaCH3COO) would work with H2O as well...
same for this
(Cu(NO3)2•2.5H2O)

These are acid-base, and I am pretty new to them, could I get some clarifications? Thanks
 
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jigglywiggly said:
So like say you have (AlK(SO4)2•12H2O)
And then how does the reaction go?

What reaction?

Please ask homework (and homework type) questions in appropriate forum.
 
Sorry, and It's just reacting with plain o'll water.
 
So you are asking about dissolution and dissociation.

In most cases dissociation is just about separating ions. What ions do you see in the alum molecule?

Don't worry about water of crystallization - it will just became part of the solution, there is already plenty of water around.
 
Just Al3+ K- and SO4 2-
 
No such thing as K-.

So if you have Al3+, why do you try to put something like AlOH between products?

Are you expected to know all the details of cation hydrolysis in such solutions?
 
Yeah I believe so.
 
That's a tricky thing - Al3+ creates a series of complexes, 4 at least (or rather I have equilibrium constants for 4 reactions). But these are things like Al3(OH)45+ - I don't think anybody by graduate students should worry about them.
 
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