John Q Public said:
Still trying to get a handle on all of this. Does everyone agree that transmission through a medium is true transmission and not absorption/re-emission? If the consensus is the latter then I am totally lost here.
It is true transmission.
John Q Public said:
The refraction and slowing down at the medium surfaces is fascinating. There are some nice comments about the electric field interactions between the photon and the medium atoms propagating the EM wave and I can accept that at face value, at least for the moment. Since each material has a different refractive index and each material has a different molecular structure that supports the fact that the molecular structure is interacting with the photon/wave to change it's direction. How does the refraction occur at the surface? The photon/wave is changing direction the moment it enters the material, and keeps that direction until it exits, at which point it resumes it's original direction.
I think we are straying into thinking of a photon as a particle here rather than a wave. The particle nature of the photon doesn't really enter the picture in the case of transmission, since there is no localised interaction as there is in the case of absorption and re-emission. Refraction occurs purely because part of the wavefront slows down, to maintain continuity at the interface, the wave must change direction as it crosses the interface.
John Q Public said:
If the photon/wave is slowing down then is it safe to say it is imparting energy to the medium to set up the dipole in the medium atoms?
The wave does impart energy to the medium, but it gets it all back in the end (i.e. the interaction is elastic). The imparting of energy has nothing to do with the speed of the wave however.
John Q Public said:
Also, if the medium is amorphous (glass) then how in the heck does the photon/wave keep the same direction as it moves from molecule to molecule in the structure of the medium? It's not like there is a well laid out path of molecules to relay dipoles along the refractive path. By definition glass has no long range ordered molecular structure. This theory seems to have the photon going in whatever direction the molecular structure takes it, yet all the photons passing through the material take the same path relative to their entry point (preserving the image we see looking through the glass).
The key to understanding photon transmission is that is an entirely non-resonant process - there is no localised interaction between photons and atoms, so we can explain everything using waves. Since electronic wavefunctions fill the entire medium, what we are essentially doing is expressing photon transmission as a "ripple" in the electronic wavefunctions that permeate through the medium. There is no need for any precise arrangement of the atoms and molecules themselves.
Again, reiterating my earlier points, there is no point making the distinction between a "photon" ripple and a "dipole" ripple. The important thing is that there is a ripple.
John Q Public said:
Lastly I am wondering about the e field interaction. If ANY energy is lost during the interaction then the photon cannot come out of the material with the same energy it entered. Is it possible for all these interactions to be perfectly lossless? How would the loss of energy manifest itself? It seems the frequency of the exiting photon would have to come down.
All energy imparted to the medium is temporary in the case of a lossless medium. Real media will have losses because, in a real atom, there is still a probability (sometimes significant) that a photon WILL undergo a localised interaction, be it an absorption event or an elastic scattering event. These losses however is a reduction in the
number of photons, not the energy of each individual photon.
Some interactions, such as Raman scattering will result in photons losing energy, and thus reducing their frequency.
I apologise if my recent responses seem a bit incoherent compared to my earlier ones, but this was an old thread recently "resurrected" as it were and my brain has had to start over

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Claude.