Suppose we think for a moment in terms of the Copenhagen interpretation. Then we couldn't say anything about whether photons are emitted one-by-one. We observe events, but we cannot say anything about whatever we say cause these measurement events, except at the point of measurement. So nothing about before the measurement. Duh, that includes the time of emission. Indeed, all we can talk about are statistics of the times (and places) at which events are observed. We cannot from the empirical statistics of observed events conclude that the statistics of unobserved emitted events are the same. It takes two, preparation and measurement, to QM.
The Copenhagen interpretation has gone out of style, but it concentrates the mind on what experiment can be imagined to justify. There are indeed reasons why the Copenhagen interpretation went out of style (inter alia, I think people really don't like to be so minimalist about causality), but there are also reasons why it remained pre-eminent for 50 years. It's dangerous to say "The Copenhagen interpretation would say ...", because Copenhagen is rather multifaceted, but, for here: the quantum state associated with a given preparation apparatus does no more than usefully summarize what statistics of event timings we will observe with various different kinds of measurement apparatus.
To briefly mention Bible Thumper's "sending an electron directly at another, then recording the resultant (260nm UV) photon that's emitted", how could we know when the electrons are emitted, without measuring them, hence changing the experiment?
Those who have seen earlier posts of mine will know that I am willing to go beyond the Copenhagen interpretation's rather minimal commitments. The double-slit experiment is a consequence of interference of a field (of a specialized, probabilistic kind, called a random field, because how should this stuff be trivial?). Events are caused by the field acting on the thermodynamically nontrivial "measurement" apparatus, which has been tuned to go from a metastable thermodynamic state to a different thermodynamic state that can be macroscopically distinguished. The inverse problem of constructing a random field model (or a quantum field model) from a finite number of event timings is of course underdetermined unless we make quite strong auxiliary assumptions. So it's best just to worry about times of emission unless you have a strong constitution.