Frabjous said:
No, particle velocity. A sound wave moves at velocity c. It gives the air a particle velocity u at the continuum level.
Yes, a sound wave moves at velocity c, and that velocity is relative to an inertial frame of reference in which the medium is stationary.
Despite molecular theory and statistical mechanics establishing that the molecules are moving randomly at a mean speed of around Mach 1, with a mean free path of around 50 nm, the medium is considered to be stationary
In that frame of reference, air is considered as a continuum in which, to quote Gupta[1],
"
This is called the continuum concept, that is, the matter is uniformly and continuously distributed and not made up of pebble-like molecules followed with space. "
There are clearly two realms in which the properties of gas, like air, can be studied: the thermodynamic, or "macroscopic" realm in which the gas behaves as a continuum and is described in terms of pressure, temperature, and density, and the molecular realm, in which it behaves like a collection of molecules and is described in terms of velocity, momentum, size and mean free path.
The two realms appear to be distinguished the size of the system under discussion relative to the mean free path of the molecules.
In the thermodynamic realm there is no useful concept of particles.
In molecular theory, the only particles are molecules. Therefore the use of particle velocity is not useful in the discussion of the velocity of sound waves in air.
In neither realm does it contain particles that are not molecules, so I am not sure in which context the term "particle velocity" is being used in the context of sound waves in air.
[1] Gupta S. C., (2011) Thermodynamics, Dorling Kindersley (India) Pvt. Ltd. p. 4