Um...
http://hyperphysics.phy-astr.gsu.edu/hbase/tables/fermi.html#c2. A simple google would've shown that the numbers are fine and the energy is right within an order of magnitude.
I really think you're just getting confused with definitions. In E&M, we
start by defining an ideal case of a conductor to be a material with sigma=infinity that expels all electric fields so by necessity it must have infinite free electrons. We use it to model conductors to get a good guess at what happens because the ideal conductor approximation works in low energy, high conductivity limits. The reality is that no conductor truly has infinite free electrons or infinite conductivity. If that were true, we would never be able to pass current through a wire.
What you've been asking us is what happens at high electric field, i.e. high energies. Well, as I've shown, for the best of conductors, you won't get to the point you are considering because other effects happen at more reasonable energies such as arcing or field emission as ZapperZ said that will break the model of a stable conductor. For other materials with fewer free electrons like semi-conductors, high electric fields tend to rip rip apart molecules or effect the substance on an atomic level changing its properties and/or destroying it completely. Thus you are not actually looking at the conductor/semi-conductor; it's something else.
In summary, perfect conductors expel all electric fields,
real conductors fight electric fields within their capabilities and tolerances resulting in properties such as conductivity and dielectric constants, and relatively high electric fields tend to destroy what you're trying to study.