How to prove solution to Fick's second law by substitution

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Homework Help Overview

The original poster attempts to prove the validity of a solution to Fick's second law by substitution, focusing on the differential equation involving concentration over time and space. The context involves understanding the mathematical properties of the error function and its derivatives in relation to the equation.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss differentiating the proposed solution with respect to time and space, questioning how to handle the integral involved in the error function. There is also a focus on the implications of the fundamental theorem of calculus in this context.

Discussion Status

Some participants have provided guidance on differentiation techniques, while others are exploring the implications of changing limits in integrals. The discussion reflects a mix of interpretations and attempts to clarify the mathematical steps involved without reaching a consensus.

Contextual Notes

There are indications of confusion regarding the application of the error function and its derivatives, as well as the relationship between the variables involved in the equation. The original poster notes a lack of clarity on how to proceed with the integral and its limits.

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Homework Statement


I am to prove that a solution to the differential equation Fick's second law is valid by substitution.

Homework Equations


Fick's second law:
\frac{\partial C}{\partial t} = \frac{\partial}{\partial x} \left( D \frac{C}{\partial x} \right)
Solution to Fick's second law:
C(x,t) = \left( \frac{C_1 + C_2}{2} \right) - \left( \frac{C_1 - C_2}{2} \right) \text{erf} \left( \frac{x}{2 \sqrt{Dt}} \right)
The (Gauss) error function (erf) which I found online:
\text{erf}(z) = \frac{2}{\sqrt{\pi}} \int_o^z e^{-y^2} dy

The Attempt at a Solution


I presume I am supposed to differentiate the proposed solution with respect to t once and compare it to the proposed solution differentiated twice with respect to x? But I am not sure how i shall handle the integral.

Can someone help me/point me to literature or give me some pointers on how to proceed?
 
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If you have taken Calculus, then you should know "the fundamental theorem of Calculus"-
\frac{d}{dx} \int_a^x f(t) dt= f(x)
 
@HallsofIvy - Thanks for a reply. The problem bugging me though, is that i do not have x, but \frac{x}{2\sqrt{Dt}}, such that:

\frac{2}{\sqrt{\pi}} \frac{\partial}{\partial x} \int_0^{\frac{x}{2\sqrt{Dt}}} e^{-y^2}dy
 
Is this the correct change of limits and function of the integral?
<br /> <br /> \frac{\partial}{\partial x} C(x,t) = -B \frac{\partial}{\partial x}\int_0^{\frac{x}{2\sqrt{Dt}}} e^{-y^2}dy = -B \frac{\partial}{\partial x} \int_0^x e^{-y^2\left(4Dt \right)^{-1}}dy = -B e^{-x^2\left(4Dt \right)^{-1}}\\<br /> \frac{\partial^2}{\partial^2 x}C(x,t) = -B \frac{\partial}{\partial x} e^{-x^2\left(4Dt \right)^{-1}} = -B e^{-x^2\left(4Dt \right)^{-1}} \frac{\partial}{\partial x}\left( -x^2\left(4Dt \right)^{-1} \right) = B \frac{2}{Dt}\cdot x e^{-x^2\left(4Dt \right)^{-1}}<br />
 
Last edited:
Solved it!

I finally understood how it worked :wink:

<br /> <br /> D\frac{\partial}{\partial x} C(x,t) = -BD \frac{\partial}{\partial x}\int_0^{\frac{x}{2\sqrt{Dt}}} e^{-y^2}dy = -BD e^{-\left(\frac{x}{2\sqrt{Dt}}\right)^2} \frac{\partial}{\partial x} \left(\frac{x}{2\sqrt{Dt}}\right) = -BD e^{-\frac{x^2}{4Dt}} \left(\frac{1}{2\sqrt{Dt}}\right) \\= \frac{-BD}{2\sqrt{Dt}} e^{-\frac{x^2}{4Dt}} \\<br /> \frac{\partial}{\partial x} \left( D \frac{C(x,t)}{\partial x} \right) = \frac{\partial}{\partial x} \frac{-BD}{2\sqrt{Dt}} e^{-\frac{x^2}{4Dt}} = \frac{-BD}{2\sqrt{Dt}} e^{-\frac{x^2}{4Dt}} \frac{\partial}{\partial x} \left( - \frac{x^2}{4Dt} \right) \\= \frac{BDx}{4}\left( Dt \right)^{-\frac{3}{2}}e^{-\frac{x^2}{4Dt}}\\<br /> <br /> \frac{\partial}{\partial t} = -B \frac{\partial}{\partial t}\int_0^{\frac{x}{2\sqrt{Dt}}} e^{-y^2}dy = -B e^{-\left(\frac{x}{2\sqrt{Dt}}\right)^2} \frac{\partial}{\partial t} \left(\frac{x}{2\sqrt{Dt}}\right) = -B e^{-\left(\frac{x}{2\sqrt{Dt}}\right)^2} \left( - \frac{Dx}{4(Dt)^{3/2}} \right) \\= \frac{BDx}{4}\left( Dt \right)^{-\frac{3}{2}}e^{-\frac{x^2}{4Dt}} \qquad \square<br /> <br />
 
Last edited:

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