Hydrofluoric Acid + Silicon Dioxide Reaction Explained

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SUMMARY

The reaction between gaseous hydrofluoric acid (HF) and solid silicon dioxide (SiO2) does not yield the expected products as initially proposed. The correct understanding of the valence electrons is crucial, with silicon (Si) exhibiting a +4 oxidation state in this context. The confusion arises from the nature of the reaction, which is not a simple double replacement due to the solid-state of SiO2 and the gaseous nature of HF. Proper memorization of chemical rules and periodic table trends is essential for accurate predictions in such reactions.

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  • Understanding of chemical reactions, specifically double replacement reactions.
  • Knowledge of oxidation states and valence electrons in elements.
  • Familiarity with the periodic table and its trends.
  • Basic principles of solid-state chemistry.
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  • Research the properties and reactions of silicon compounds, particularly silicon dioxide.
  • Explore the behavior of gaseous acids in reactions with solid substrates.
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Gaseous hydrofluoric acid reacts with solid silicon dioxide.
My work (did a double replacement):
HF+SiO2------>H2O+SiF

But this doesn't look right. Why?
1. It looks weird.
2. How much valence electrons is Si supposed to have?
3. We're not dealing with solutions.


Anyone know the answer?
 
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ohhh man i do really bad in these. You pretty much have to memorize lots of rules.
I can answer #2 though, since O = -2 and the substance is a solid, then the compound is not an ion thus Si being 4+ . Or...just count from left to right in periodic table. Noting that Si was the cation.
 

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