Hydrogenation of alkynes and alkenes

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Catalytic hydrogenation of alkenes and alkynes typically involves H2 and a Pd catalyst for syn addition. For alkynes, the addition of quinoline and CaCO3-doped Pd catalyst is necessary to halt reduction at the alkene stage. Without quinoline, using just H2 and Pd on alkynes results in full hydrogenation to a tetrahydrogenated alkane. This highlights the importance of specific reagents in controlling the extent of hydrogenation. Understanding these reactions is crucial for selective synthesis in organic chemistry.
tandoorichicken
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Hello.

I have a question about catalytic hydrogenation reagents. I know that you can perform syn hydrogenation of alkenes with H2 and Pd catalyst, and the same goes for alkynes except for the addition of quinoline (and CaCO3 doped Pd catalyst).

I was wondering if there is a reaction with alkynes and just H2 and Pd catalyst?
 
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got it. quinoline stops reduction at the alkene stage. reacting alkyne with direct H2 and Pd gives a tetrahydrogenated alkane.
 
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