An electron is described by a quantum state. This quantum state has all the information about the electron, depending on the QS you can have an electron with some definite momentum or an electron with some definite position (although these two cases are usually taken as "ideal" and not physically possible).
Essentially, given an arbitrary quantum state ##\left|\psi\right>## there exists an operator that creates an electron in such state.
Of course, there are relations between the states, so you can find a relation between the different creation operators (for example if you have a state ##\psi## that is a linear combination of states ##\psi_1## and ##\psi_2##, then the creation operators will also be linearly dependent).
So for me, the question of whether the electron has a definite momentum or not has nothing to do with the creation operators, but with its state. And it is exactly equivalent to asking whether a non-relativistic wave function (the usual you have probably studied in quantum physics) has a definite momentum or not.