Lab report questions, gas thermometer

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SUMMARY

The discussion centers on the calibration and functionality of gas thermometers, specifically comparing mercury and water as the liquid medium. Participants concluded that mercury is preferred due to its lower density change (2% from 0°C to 100°C) compared to water, which could spill or freeze in extreme temperatures. The accuracy of mercury thermometers is attributed to the assumption that the liquid will equilibrate with the air temperature, mitigating potential measurement errors. The conversation highlights the importance of understanding liquid properties in thermometric applications.

PREREQUISITES
  • Understanding of gas thermometers and their calibration methods
  • Knowledge of liquid density and its temperature dependence
  • Familiarity with thermal expansion concepts
  • Basic principles of heat capacity and its effects on measurement accuracy
NEXT STEPS
  • Research the principles of gas thermometers and their calibration techniques
  • Study the effects of temperature on liquid density, focusing on mercury and water
  • Explore the concept of thermal expansion and its implications for measurement accuracy
  • Investigate alternative liquids for thermometric applications and their properties
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Students and educators in physics, laboratory technicians, and anyone involved in thermometric research or applications will benefit from this discussion.

fluidistic
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Hi PF!
I have a lab report to do about a gas thermometer experience that I couldn't do. I'm very saddened about this because I should have manipulate mercury but the earlier group broke a container of mercury and so the class had to be disinfected and closed for some days.
Basically it consists of calibrating a gas (air) thermometer in order to evaluate the room temperature. (This picture explains how is the device : http://www.shef.ac.uk/physics/teaching/phy001/fig1.gif . For further explanations of what is a gas thermometer, read this : http://en.wikipedia.org/wiki/Gas_thermometer)
So the professor gave us the results the first class obtained and told us to work on it to get the final result. Furthermore he asked a few questions to be answered in the lab report.
One of these questions is : What if the liquid used is water instead of mercury?
My thought is that water would go up more than mercury because it is quite less dense. So as the column of the thermometer is only 47 cm and that the mercury went up to 16.5 cm for a gas temperature of 98,488 °C, the thermometer of water wouldn't be of any use for high temperatures (it would go up more than 47 cm and spread on the floor). Am I right?

For low temperatures (0°C to 8°C), the water has a density's minimum at 4°C. Does it affect the lecture of measures? Also, if the air is say at -20°C, will the water freeze? Or not if I take the measure fast? I know it has a somewhat a low heat capacity so I wonder if the air temperature has a big effect.
Another doubt: the mercury seems to have to big heat capacity, so when I heat up the air to 100°C, the mercury expand quite a lot and the column of mercury should go higher than if it were at room temperature. Does it makes “false” results?
Is there anything else I can add to answer the professor's question?
 
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Ok maybe I've asked too many questions.
I don't understand why the gas thermometer that uses mercury as liquid is accurate. Indeed, when we heat the gas from 25°C to 100°C, the mercury that is in contact with the gas also heat up and expands. Meaning that the column of mercury is higher than it should. As we read the temperature looking at the height of the mercury's column, it is erroneous.
We should take this in count when analyzing the data but we do not. I feel I'm missing something here.
 
Hi,

Usually the change in density, with temperature, of liquids and solids is neglected because it is small. For mercury, it's a 2% change from 0C to 100C (13.60 vs. 13.35 g/cc).

Also, we should probably assume the temperature changes slowly enough so that the liquid will be the same temperature as the air. So you're right about water freezing below 0C.

Other issues with water: as you said, it could spill out of the tube (if the tube end is open) or fill up the tube (if the tube end is closed). Either way, a longer tube is required to get a reading.
 
Redbelly98 said:
Hi,

Usually the change in density, with temperature, of liquids and solids is neglected because it is small. For mercury, it's a 2% change from 0C to 100C (13.60 vs. 13.35 g/cc).

Also, we should probably assume the temperature changes slowly enough so that the liquid will be the same temperature as the air. So you're right about water freezing below 0C.

Other issues with water: as you said, it could spill out of the tube (if the tube end is open) or fill up the tube (if the tube end is closed). Either way, a longer tube is required to get a reading.
Thank you very much! I wasn't aware that liquid's density change with temperature was so "unnoticeable".
Thanks for the informations, now I can do the conclusion of my report. :smile:
 

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