Landau theory: why does a m^3 term implies first order transition phase

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Discussion Overview

The discussion revolves around the implications of adding a cubic term (m3) to the Landau free energy in the context of phase transitions, specifically focusing on whether this addition indicates a first-order transition. Participants explore the relationship between the free energy expression and the characteristics of phase transitions, including discontinuities in entropy and latent heat.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants question why the inclusion of a m3 term in the Landau free energy suggests a first-order transition, noting potential implications for discontinuities in entropy and latent heat.
  • One participant clarifies that m refers to the magnetic moment, which serves as the order parameter in this context.
  • A suggestion is made to plot the free energy function F = t m2 + b m3 + m4 for various values of t and b to visualize the transition, particularly noting that as b increases, the minimum of the free energy may jump from zero to a finite value, indicating a first-order transition.

Areas of Agreement / Disagreement

Participants express uncertainty about the implications of the m3 term, and while some points are clarified, the discussion does not reach a consensus on the relationship between the cubic term and first-order transitions.

Contextual Notes

The discussion includes assumptions about the behavior of the free energy function and the conditions under which a first-order transition is identified, which remain unresolved.

IRobot
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Hi,

I am not sure it is the right subcategory to post a question on statistical physics. But anyway, I read a couple of times that adding a m^3 to the Landau free energy implies that we may observe a first order transition phase, but I don't see why. Maybe it does imply some discontinuity in the entropy, latent heat, but I am not seeing that.
 
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IRobot said:
Hi,

I am not sure it is the right subcategory to post a question on statistical physics. But anyway, I read a couple of times that adding a m^3 to the Landau free energy implies that we may observe a first order transition phase, but I don't see why. Maybe it does imply some discontinuity in the entropy, latent heat, but I am not seeing that.

What is m? Mass, magnetic moment?
 
M is the magnetic moment, the order parameter.
 
IRobot said:
Hi,

I am not sure it is the right subcategory to post a question on statistical physics. But anyway, I read a couple of times that adding a m^3 to the Landau free energy implies that we may observe a first order transition phase, but I don't see why. Maybe it does imply some discontinuity in the entropy, latent heat, but I am not seeing that.

Try to make a plot of a sample free energy:
[itex]F=t m^2 + b m^3 + m^4[/itex]
for different values of t and b? In particular, try a fixed t at some finite value and varies b.

When t >> b, the free energy is minimum is at m=0, then as you increase b, at some point, the minimum JUMPS from 0 to some finite value. That, by definition, is a first order transition where the order parameter has a discontinuous jump.
 
Thanks, you made it clear ;)
 

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