Latent heat vaporization vs fusion

AI Thread Summary
The discussion centers on why the latent heat of vaporization is greater than that of fusion. It highlights that in the liquid state, atoms are not significantly far apart, leading to minimal changes in density during melting. The comparison of water's density, which is higher in liquid form than in solid form, is noted as an example of anomalous behavior. Participants agree that the transition from liquid to gas involves a more substantial change in density, indicating greater intermolecular distance. Overall, the conversation emphasizes the energy requirements for phase changes and the implications of intermolecular forces.
SandeshPhy
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Why is the latent heat of vaporisation greater than that of fusion(melting)?
I mean in liquid state,atoms are already far apart, so it must require less energy to make them gas(far apart) as forces(electric in nature) between molecules decrease with distance.
 
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I don't think that atoms in liquid are far apart. Actually, when solid melts there is small change in density, implying that there isn't quite much change in intermolecular distance. e.g water is virtually densor than ice
 
ZealScience said:
I don't think that atoms in liquid are far apart. Actually, when solid melts there is small change in density, implying that there isn't quite much change in intermolecular distance. e.g water is virtually densor than ice

That is only the case for water due to anomalous behavior.
Yes there a change in density from liquid to gas change while there is little from solid to liquid.
 
And density of a phase is a god indication of intermolecular distance.
 
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