Linear Operators: Relationship Between Action on Kets & Bras

aaaa202
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This is basically more of a math question than a physics-question, but I'm sure you can answer it. My question is about linear operators. If I write an operator H as (<al and lb> being vectors):
<alHlb>
What is then the relationship between H action the ket and H action on the bra. Is this for example true:
<alHlb> = H <alb>
Which rules determine how the operator acts?
Can it be thought of as a scalar such that instead:
<alHlb> = H* <alb>
My question came naturally as I was applying the position-state <xl to the left side of the schrödinger-equation (H being the hamiltonian and lψ(t)> the state vector:
<xlHlψ(t)>
does this equal to:
H<xlψ(t)>
I reckon it must because I've seen it work the other way around, but why is it precisely so. Doesn't it have to do with the fact that H is hermitian?
 
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aaaa202 said:
This is basically more of a math question than a physics-question, but I'm sure you can answer it. My question is about linear operators. If I write an operator H as (<al and lb> being vectors):
<alHlb>
What is then the relationship between H action the ket and H action on the bra. Is this for example true:
<alHlb> = H <alb>
Which rules determine how the operator acts?
Can it be thought of as a scalar such that instead:
<alHlb> = H* <alb>
My question came naturally as I was applying the position-state <xl to the left side of the schrödinger-equation (H being the hamiltonian and lψ(t)> the state vector:
<xlHlψ(t)>
does this equal to:
H<xlψ(t)>
I reckon it must because I've seen it work the other way around, but why is it precisely so. Doesn't it have to do with the fact that H is hermitian?

You can't move the operator outside the inner product like that.
An operator is a mapping between vector spaces. Think of it like
a machine: you give it one vector and it gives you another vector back.
However, the inner product \langle a | b \rangle is a scalar,
so in your equation
<br /> \langle a | H | b \rangle ~=~ H \langle a | b \rangle<br />
you have a scalar on the LHS but an operator on the RHS,
which is mathematical nonsense, in general.
 


But in the question about the schr. equation. Does this not equal to?
<xlHlψ(t)>
<=>
H<xlψ(t)>
<xl is a position eigen-state and lψ(t)> the state vector.
 
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If we release an electron around a positively charged sphere, the initial state of electron is a linear combination of Hydrogen-like states. According to quantum mechanics, evolution of time would not change this initial state because the potential is time independent. However, classically we expect the electron to collide with the sphere. So, it seems that the quantum and classics predict different behaviours!
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