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I'm trying to understand this concept. For example if there is a wooden sphere and we said that all of its mass is concentrated at a single point, can I think of this as the mass of the entire sphere being contained in one of its atoms?
Minor quibble- it's not a mathematical device, it's a *conceptual* device. Replacing an extended object with a point object located at the center of mass, having the same mass as the original object is a conceptual simplification.