Material balance- purge cycle help

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The discussion centers on calculating the purge stream flow rate and composition to limit CO2 in a hydrogen reduction process. The reaction involves reducing Fe2O3 to metallic iron using hydrogen, with a recycling system that includes a purge to manage CO2 impurities. A material balance approach is used, leading to the conclusion that the flow rate of the purge stream can be derived from the CO2 balance equations. The participant expresses confusion about why the purge stream flow rate is considered equal to the fresh feed flow rate despite the presence of recycled CO2 and other outputs. Clarification on the material balance method and its implications for the flow rates is requested.
simon.23
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Hydrogen is used to reduce 2.3 tonne per hour, Fe2O3 to metallic iron according to the reaction

Fe_{2}O_{3} + 3H_{2} = 2Fe + 3H_{2}O

The water is condensed and the unreacted hydrogen is recycled (see diagram attached). Because the hydrogen in the fresh feed contains 1.1% CO2 as an impurity, some of the unreacted hydrogen must be purged. Calculate the flow rate and the composition of the purge stream required to limit the CO2 in the reactor feed to 2.8% if the ratio of recycle to fresh feed is 11:2 on a molar basis.
MW(Fe) = 55.85, MW(H) = 1.01, MW(O) = 16.00.


I am really struggling to get to grips with this question, ( struggling with material balance overall!)

I can do dimple material balance however for things with a recycle stream or purge stream, really confuses me.

I have the solution which I will post up, but I still don't get 'why' it is solved in this manner. I would really appreciated it, if someone explains to me why. Or if you have simpler way of working the flow rate of the purge stream?

thank you,
 

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SOLUTION;

CO2- Balance;


0.011x + y = 6.5x (0.028)

y = 0.0171x in the recycle stream.

\frac{0.0171x}{5.5x} \times 100 = 3.1 \% of CO2 in purge stream,
100 - 3.1 = 96.9 % H2 in purge stream. Flow rate of purge:

CO2 BALANCE-

0.011x = 0.031p , x = \frac{0.031p}{0.011}

H2 Balance-
0.989x = 43.204 + 0.969p

2.787p = 43.204 + 0.969p

p = 23.76 kmol h^{-1}

Firstly, I don't get why the flow rate of the purge stream is equal to the flow rate of the fresh feed stream?

Surely it won't be the same, as some CO2 is being recycled? Your also loosing water and Fe iron, from the fresh fee, you have two outputs, so surely the flow rate of the fresh feed would be more than the flow rate of the purge stream, so you can't set them equal to each other?
 

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