- #1

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for adiabatic process,

pV

^{γ}=const

What is the physical meaning of the constant at the Rhs of this equality?

Many thanks.

- Thread starter Sunfire
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- #1

- 221

- 4

for adiabatic process,

pV

What is the physical meaning of the constant at the Rhs of this equality?

Many thanks.

- #2

- 175

- 0

Note that there might still be work.

- #3

- 221

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Because all states of the system are equal to this constant, it has to have a meaning... if it is constant energy, the units won't match due to the gamma exponent

E.g. it is not energy, but something else. Any ideas?

- #4

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const = (pV) V

e.g. energy multiplied by some volume fraction

probably energy density of sorts?

- #5

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In other words, if you put a system into a specific state with pressure P and volume V, then adiabatically change the pressure or volume, then the new pressure P` and volume V` will be related to the original by PV

- #6

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It is an experimental fact that for many processes there is both change of pressure and of volume for the working substance (which does not have to be a gas)

Thus the laws relating to constant pressure or constant volume processes are not applicable.

If we experimentally plot a process on a PV diagram we find that very often it is of the form

PV

(Note here n is not gamma)

It is better to plot logP against logV this yields a straight line of slope -n

logP = log C - nlogV

Which is a straight line of slope -n and intercept logC on the logP axis.

So this is the meaning of the constant C - It is a quantity inherent in the system that is preserved in any such change.

This type of process is called the Polytropic Process.

You should look it up.

Please also note that

Putting n = 0 yields a constant pressure process (horizontal line on a PV diagram)

Putting n = ∞ yields a constant volume process (vertical line on a PV diagram)

It is usual for the change in pressure to be in the opposite direction from the change in volume, in which case n is positive and the slope is negative.

However it is possible to devise a system in which n is negative.

Gamma is a particular case of n for an adiabatic process. It can be shown that gamma is the ratio of the specific heats for an ideal gas.

γ = C

- #7

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Studiot,

"So this is the meaning of the constant C - It is a quantity inherent in the system that is preserved in any such change."

This is EXACTLY what I am interested in. What is this inherent quantity? Does it have a name? How can it be determined for a given system, etc. My feeling is that C is a fundamental quantity for a given system (or a gas) and understanding its meaning can be very useful in understanding all other states the system can be in.

- #8

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It's just the antilog of the y intercept on a logp v logV diagram.

Since log1 = 0 the (antilog)value of C gives the base pressure for unit volume in the polytropic law.

Since both pressure and volume vary with the polytropic law you cannot assign anything further of significance to it as you could to the constant in the special case of Boyles law.

- #9

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- #10

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Is there something that need further explanation here? The adiabatic equation is just a special case of the more general polytropic process.

- #11

Q_Goest

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A polytropic process for a gas is one in which a gas is compressed or expanded, heated or cooled. RoyMech.co.uk has a decent article on it.

An adiabatic process is simply one that has no heat entering or leaving the gas, so the only energy going into or coming out of the gas is work. If there's no heat transfer into or out of the gas, and work is being done on or by the gas, it is also an isentropic process. For an adiabatic process, the polytropic exponent, n, becomes the ratio of specific heats for the gas. So the equation would become:

PV

Note that k is the ratio of specific heats, C

Some of the other values for n were pointed out by Studiot and can be found on the Wikipedia article. Another one that's of interest is when n = 1. In that case, the temperature of the process does not change. It is an isothermal process. So if the gas is being compressed or expanded and the gas remains at a constant temperature, heat has to be removed (during compression) or added (during expansion) to keep the temperature constant.

A polytropic process and the general equation that describes it (PV

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